Abstract: This study investigated a strategy of blending lead-laden sludge and Al-rich precursors to reduce the release of metals from the stabilized products. Using PbO as the simulated lead-laden sludge to sinter with γ-Al2O3 by Pb:Al molar ratios of 1:2 and 1:12, PbAl2O4 and PbAl12O19 were formed as final products during the sintering process, respectively. By firing the PbO + γ-Al2O3 mixtures with different Pb/Al molar ratios at 600 to 1000 °C, the lead transformation was determined through X-ray diffraction (XRD) data. In Pb/Al molar ratio of 1/2 system, the formation of PbAl2O4 is initiated at 700 °C, but an effective formation was observed above 750 °C. An intermediate phase, Pb9Al8O21, was detected in the temperature range of 800-900 °C. However, different incorporation behavior for sintering PbO with Al-rich precursors at a Pb/Al molar ratio of 1/12 was observed during the formation of PbAl12O19 in this system. In the sintering process, both temperature and time effect on the formation of PbAl2O4 and PbAl12O19 phases were estimated. Finally, a prolonged leaching test modified from the U.S. Environmental Protection Agency-s toxicity characteristic leaching procedure (TCLP) was used to evaluate the durability of PbO, Pb9Al8O21, PbAl2O4 and PbAl12O19 phases. Comparison for the leaching results of the four phases demonstrated the higher intrinsic resistance of PbAl12O19 against acid attack.
Abstract: This investigation examines the effect of the sintering
temperature curve in manufactured nickel powder capillary structure
(wick) for a loop heat pipe (LHP). The sintering temperature curve is
composed of a region of increasing temperature; a region of constant
temperature and a region of declining temperature. The most important
region is that in which the temperature increases, as an index in the
stage in which the temperature increases. The wick of nickel powder is
manufactured in the stage of fixed sintering temperature and the time
between the stage of constant temperature and the stage of falling
temperature. When the slope of the curve in the region of increasing
temperature is unity (equivalent to 10 °C/min), the structure of the
wick is complete and the heat transfer performance is optimal. The
result of experiment test demonstrates that the heat transfer
performance is optimal at 320W; the minimal total thermal resistance
is approximately 0.18°C/W, and the heat flux is 17W/cm2; the internal
parameters of the wick are an effective pore radius of 3.1 μm, a
permeability of 3.25×10-13m2 and a porosity of 71%.
Abstract: Commercial hydroxyapatite (HA) was reinforced by
adding 2, 5, and 10 wt % of 28.5%CaO-28.5%P2O5-38%Na2 O-
5%CaF2 based glass and then sintered. Although HA shows good
biocompatibility with the human body, its applications are limited to
non load-bearing areas and coatings due to its poor mechanical
properties. These mechanical properties can be improved
substantially with addition of glass ceramics by sintering. In this
study, the effects of sintering hydroxyapatite with above specified
phosphate glass additions are quantified. Each composition was
sintered over a range of temperatures. Scanning electron microscopy
and x-ray diffraction were used to characterize the microstructure and
phases of the composites. The density, microhardness, and
compressive strength were measured using Archimedes Principle,
Vickers Microhardness Tester (at 0.98 N), and Instron Universal
Testing Machine (cross speed of 0.5 mm/min) respectively. These
results were used to indicate which composition provided suitable
material for use in hard tissue replacement. Composites containing 10
wt % glass additions formed dense HA/TCP (tricalcium phosphate)
composite materials possessing good compressive strength and
hardness than HA. In-vitro bioactivity was assessed by evaluating
changes in pH and Ca2+ ion concentration of SBF-simulated body
fluid on immersion of these composites in it for two weeks.
Abstract: This work presents the results of a study carried out to
determine the sliding wear behavior and its effect on the process
parameters of components manufactured by direct metal laser
sintering (DMLS). A standard procedure and specimen had been used
in the present study to find the wear behavior. Using Taguchi-s
experimental technique, an orthogonal array of modified L8 had been
developed. Sliding wear testing using pin-on-disk machine was
carried out and analysis of variance (ANOVA) technique was used to
investigate the effect of process parameters and to identify the main
process parameter that influences the properties of wear behavior on
the DMLS components. It has been found that part orientation, one
of the selected process parameter had more influence on wear as
compared to other selected process parameters.
Abstract: In recent times there has been a growing interest in the
development of quasi-two-dimensional niobium pentoxide (Nb2O5)
as a semiconductor for the potential electronic applications such as
capacitors, filtration, dye-sensitised solar cells and gas sensing
platforms. Therefore once the purpose is established, Nb2O5 can be
prepared in a number of nano- and sub-micron-structural
morphologies that include rods, wires, belts and tubes. In this study
films of Nb2O5 were prepared on gold plated silicon substrate using
spin-coating technique and subsequently by mechanical exfoliation.
The reason this method was employed was to achieve layers of less
than 15nm in thickness. The sintering temperature of the specimen
was 800oC. The morphology and structural characteristics of the
films were analyzed by Atomic Force Microscopy (AFM), Raman
Spectroscopy, X-ray Photoelectron Spectroscopy (XPS).
Abstract: The forming process parameters of Selective Laser
Sintering(SLS) directly affect the forming efficiency and forming
quality. Therefore, to determine reasonable process parameters is
particularly important. In this paper, the weight of each target of the
forming quality and efficiency is firstly calculated with the Analytic
Hierarchy Process. And then the size of each target is measured by
orthogonal experiment. Finally, the sum of the product of each target
with the weight is compared to the process parameters in each group
and obtained the optimal molding process parameters.
Abstract: In this study, mechanically alloyed Al 2024 powder is
densified by conventional sintering and by equal channel angular
pressing (ECAP) with and without back pressure. The powder was
encapsulated in an aluminium can for consolidation through ECAP.
The properties obtained in the compacts by conventional sintering
route and by ECAP are compared. The effect of conventional
sintering and ECAP on consolidation behaviour of powder,
microstructure, density and hardness is discussed. Room temperature
back pressure aided ECAP results in nearly full denser (97% of its
theoretical density) compact at room temperature. NanoIndentation
technique was used to determine the modulus of the consolidated
compacts.
Abstract: Recently, the advanced technologies that offer high
precision product, relative easy, economical process and also rapid
production are needed to realize the high demand of ultra precision
micro part. In our research, micromanufacturing based on soft
lithography and nanopowder injection molding was investigated. The
silicone metal pattern with ultra thick and high aspect ratio succeeds to
fabricate Polydimethylsiloxane (PDMS) micro mold. The process
followed by nanopowder injection molding (PIM) by a simple vacuum
hot press. The 17-4ph nanopowder with diameter of 100 nm, succeed
to be injected and it forms green sample microbearing with thickness,
microchannel and aspect ratio is 700μm, 60μm and 12, respectively.
Sintering process was done in 1200 C for 2 hours and heating rate
0.83oC/min. Since low powder load (45% PL) was applied to achieve
green sample fabrication, ~15% shrinkage happen in the 86% relative
density. Several improvements should be done to produce high
accuracy and full density sintered part.
Abstract: Rapid Prototyping (RP) is a technology that produces models and prototype parts from 3D CAD model data, CT/MRI scan data, and model data created from 3D object digitizing systems. There are several RP process like Stereolithography (SLA), Solid Ground Curing (SGC), Selective Laser Sintering (SLS), Fused Deposition Modeling (FDM), 3D Printing (3DP) among them SLS and FDM RP processes are used to fabricate pattern of custom cranial implant. RP technology is useful in engineering and biomedical application. This is helpful in engineering for product design, tooling and manufacture etc. RP biomedical applications are design and development of medical devices, instruments, prosthetics and implantation; it is also helpful in planning complex surgical operation. The traditional approach limits the full appreciation of various bony structure movements and therefore the custom implants produced are difficult to measure the anatomy of parts and analyze the changes in facial appearances accurately. Cranioplasty surgery is a surgical correction of a defect in cranial bone by implanting a metal or plastic replacement to restore the missing part. This paper aims to do a comparative study on the dimensional error of CAD and SLS RP Models for reconstruction of cranial defect by comparing the virtual CAD with the physical RP model of a cranial defect.