Abstract: Fuel cell grade gas-diffusion layer carbon paper (CP) electrodes are subjected to electrophoresis in N,N’-dimethylformamide (DMF) consisting of reduced graphene oxide (rGO). The rGO modified electrodes are compared with CP in a single asymmetric all-vanadium redox battery system (employing a double serpentine flow channel for each half-cell). Peak power densities improved by 4% when the rGO deposits were facing the ion-exchange membrane (cell performance was poorer when the rGO was facing the flow field). Cycling of the cells showed least degradation of the CP electrodes that were coated with rGO in comparison to pristine samples.
Abstract: This paper presents the influences on the entrainment
of serpentines by grinding and reagents during copper–nickel sulfide
flotation. The previous bench flotation tests were performed to extract
the metallic values from the ore in Yunnan Mine, China and the
relatively satisfied results with recoveries of 86.92% Cu, 54.92% Ni,
and 74.73% Pt+Pd in the concentrate were harvested at their grades of
4.02%, 3.24% and 76.61 g/t, respectively. However, the content of
MgO in the concentrate was still more than 19%. Micro-flotation tests
were conducted with the objective of figuring out the influences on the
entrainment of serpentines into the concentrate by particle size,
flocculants or depressants and collectors, as well as visual
observations in suspension by OLYMPUS camera. All the tests results
pointed to the presences of both “entrapped-in” serpentines and its
coating on the hydrophobic flocs resulted from strong collectors
(combination of butyl xanthate, butyl ammonium dithophosphate,
even after adding carboxymethyl cellulose as effective depressant.
And fine grinding may escalate the entrainment of serpentines in the
concentrate.
Abstract: This study aims to investigate the mixing behaviors of
deionized (DI) water and carboxymethyl cellulose (CMC) solutions in
C-shaped serpentine micromixers over a wide range of flow
conditions. The flow of CMC solutions exhibits shear-thinning
behaviors. Numerical simulations are performed to investigate the
effects of the mean flow speed, fluid properties and geometry
parameters on flow and mixing in the micromixers with the serpentine
channel of the same overall channel length. From the results, we can
find the following trends. When convection dominates fluid mixing,
the curvature-induced vortices enhance fluid mixing effectively. The
mixing efficiency of a micromixer consisting of semicircular C-shaped
repeating units with a smaller centerline radius is better than that of a
micromixer consisting of major segment repeating units with a larger
centerline radius. The viscosity of DI water is less than the overall
average apparent viscosity of CMC solutions, and so the effect of
curvature-induced vortices on fluid mixing in DI water is larger than
that in CMC solutions for the cases with the same mean flow speed.
Abstract: Hybrid photovoltaic thermal (PVT) collectors allow simultaneous production of electrical energy thus heat energy. There are several configurations of hybrid collectors (to produce water or air). For hybrids water collectors, there are several configurations that differ by the nature of the absorber (serpentine, tubes...). In this paper, an absorber tank is studied. The circulation of the coolant is natural (we do not use the pump). We present the obtained results in our experimental study and we analyzed the data, and then we compare the results with the theory practices. The electrical performances of the hybrid collector are compared with those of conventional photovoltaic module mounted on the same structure and measured under the same conditions.
We conducted experiments with natural circulation of the coolant (Thermosyphon), for a flow rate of 0.025kg/m².
Abstract: Crawling movement as a motive mode seen in nature
of some animals such as snakes possesses a specific syntactic and
dynamic analysis. Serpentine robot designed by inspiration from
nature and snake-s crawling motion, is regarded as a crawling robot.
In this paper, a serpentine robot with spiral motion model will be
analyzed. The purpose of this analysis is to calculate the vertical and
tangential forces along snake-s body and to determine the parameters
affecting on these forces. Two types of serpentine robots have been
designed in order to examine the achieved relations explained below.
Abstract: The morphology, mineralogical and chemical
composition of a low-grade nickel ore from Mpumalanga, South
Africa, were studied by scanning electron microscope (SEM), X-ray
diffraction (XRD) and X-ray fluorescence (XRF), respectively. The
ore was subjected to atmospheric agitation leaching using sulphuric
acid to investigate the effects of acid concentration, leaching
temperature, leaching time and particle size on extraction of nickel
and cobalt. Analyses results indicated the ore to be a saprolitic nickel
laterite belonging to the serpentine group of minerals. Sulphuric acid
was found to be able to extract nickel from the ore. Increased acid
concentration and temperature only produced low amounts of nickel
but improved cobalt extraction. As high as 77.44% Ni was achieved
when leaching a -106+75μm fraction with 4.0M acid concentration at
25oC. The kinetics of nickel leaching from the saprolitic ore were
studied and the activation energy was determined to be 18.16kJ/mol.
This indicated that nickel leaching reaction was diffusion controlled.
Abstract: In this research, the flow pattern influence on
performance of a micro PEMFC was investigated
experimentally. The investigation focused on the impacts of
bend angels and rib/channel dimensions of serpentine flow
channel pattern on the performance and investigated how they
improve the performance. The fuel cell employed for these
experiments was a micro single PEMFC with a membrane of
1.44 cm2 Nafion NRE-212. The results show that 60° and 120°
bend angles can provide the better performances at 20 and 40
sccm inlet flow rates comparing to that the conventional design.
Additionally, wider channel with narrower rib spacing gives
better performance. These results may be applied to develop
universal heuristics for the design of flow pattern of micro
PEMFC.
Abstract: This study investigated the effect of oxygen and
micro-cracking on the flotation of low grade nickel sulphide ore. The
ore treated contained serpentine minerals which have a history of
being difficult to process efficiently. The use of oxygen as a bubbling
gas has been noted to be effective because it increases the pulp
potential. The desired effect of micro cracking the ore is that the
nickel sulphide minerals will become activated and this activation
will render these minerals more susceptible to react with potassium
amyl xanthate collectors, resulting in a higher recovery of nickel and
hinder the recovery of other undesired minerals contained in the ore.
Higher nickel recoveries were obtained when pure oxygen was used
as a bubbling gas rather than the conventional air. Microwave
cracking favored the recovery of nickel.
Abstract: In the first part of the research work, an electrolyzer (10.16 cm dia and 24.13 cm height) to produce hydrogen and oxygen was constructed for single slice O2/H2 fuel cell using cation exchange membrane. The electrolyzer performance was tested with 23% NaOH, 30% NaOH, 30% KOH and 35% KOH electrolyte solution with current input 4 amp and 2.84 V from the rectifier. Rates of volume of hydrogen produced were 0.159 cm3/sec, 0.155 cm3/sec, 0.169 cm3/sec and 0.163 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution. Rates of volume of oxygen produced were 0.212 cm3/sec, 0.201 cm3/sec, 0.227 cm3/sec and 0.219 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution (1.5 L). In spite of being tested the increased concentration of electrolyte solution, the gas rate does not change significantly. Therefore, inexpensive 23% NaOH electrolyte solution was chosen to use as the electrolyte in the electrolyzer. In the second part of the research work, graphite serpentine flow plates, fiberglass end plates, stainless steel screen electrodes, silicone rubbers were made to assemble the single slice O2/H2 polymer electrolyte membrane fuel cell (PEMFC).