Abstract: This study presents an investigation of diesel vehicle particulate-phase emissions with neat ultralow sulphur diesel (B0, ULSD) and 5% waste cooking oil-based biodiesel blend (B5) in Hong Kong. A Euro VI light duty diesel vehicle was tested under transient (New European Driving Cycle (NEDC)), steady-state and idling on a chassis dynamometer. Chemical analyses including organic carbon (OC), elemental carbon (EC), as well as 30 polycyclic aromatic hydrocarbons (PAHs) and 10 oxygenated PAHs (oxy-PAHs) were conducted. The OC fuel-based emission factors (EFs) for B0 ranged from 2.86 ± 0.33 to 7.19 ± 1.51 mg/kg, and those for B5 ranged from 4.31 ± 0.64 to 15.36 ± 3.77 mg/kg, respectively. The EFs of EC were low for both fuel blends (0.25 mg/kg or below). With B5, the EFs of total PAHs were decreased as compared to B0. Specifically, B5 reduced total PAH emissions by 50.2%, 30.7%, and 15.2% over NEDC, steady-state and idling, respectively. It was found that when B5 was used, PAHs and oxy-PAHs with lower molecular weight (2 to 3 rings) were reduced whereas PAHs/oxy-PAHs with medium or high molecular weight (4 to 7 rings) were increased. Our study suggests the necessity of taking atmospheric and health factors into account for biodiesel application as an alternative motor fuel.
Abstract: Water and sediment samples from the Danube River and Moson Danube Arm (Hungary) have been collected and analyzed for contamination by 18 polycyclic aromatic hydrocarbons (PAHs) and eight trace metal(loid)s (As, Cu, Pb, Ni, Cr, Cd, Hg and Zn) in the period of 2014-2015. Moreover, the trace metal(loid) concentrations were measured in the Rába and Marcal rivers (parts of the tributary system feeding the Danube). Total PAH contents in water were found to vary from 0.016 to 0.133 µg/L and concentrations in sediments varied in the range of 0.118 mg/kg and 0.283 mg/kg. Source analysis of PAHs using diagnostic concentration ratios indicated that PAHs found in sediments were of pyrolytic origins. The dissolved trace metal and arsenic concentrations were relatively low in the surface waters. However, higher concentrations were detected in the water samples of Rába (Zn, Cu, Ni, Pb) and Marcal (As, Cu, Ni, Pb) compared to the Danube and Moson Danube. The concentrations of trace metals in sediments were higher than those found in water samples.
Abstract: Atmospheric aerosols have several important environmental impacts and health effects in point of air quality. Monitoring the PM10-bound polycyclic aromatic hydrocarbons (PAHs) could have important environmental significance and health protection aspects. Benzo(a)pyrene (BaP) is the most relevant indicator of these PAH compounds. In Hungary, the Hungarian Air Quality Network provides air quality monitoring data for several air pollutants including BaP, but these data show only the annual mean concentrations and maximum values. Seasonal variation of BaP concentrations comparing the heating and non-heating periods could have important role and difference as well. For this reason, the main objective of this study was to assess the annual concentration and seasonal variation of BaP associated with PM10 in the ambient air of Northwestern Hungary seven different sampling sites (six urban and one rural) in the sampling period of 2008–2013. A total of 1475 PM10 aerosol samples were collected in the different sampling sites and analyzed for BaP by gas chromatography method. The BaP concentrations ranged from undetected to 8 ng/m3 with the mean value range of 0.50-0.96 ng/m3 referring to all sampling sites. Relatively higher concentrations of BaP were detected in samples collected in each sampling site in the heating seasons compared with non-heating periods. The annual mean BaP concentrations were comparable with the published data of the other Hungarian sites.
Abstract: Polycyclic Aromatic Hydrocarbons (PAHs) are
formed mainly because of incomplete combustion of organic
materials during industrial, domestic activities or natural occurrence.
Their toxicity and contamination of terrestrial and aquatic ecosystem
have been established. However, with limited validity index, previous
research has focused on PAHs isomer pair ratios of variable
physicochemical properties in source identification. The objective of
this investigation was to determine the empirical validity of Pearson
Correlation Coefficient (PCC) and Cluster Analysis (CA) in PAHs
source identification along soil samples of different land uses.
Therefore, 16 PAHs grouped, as Endocrine Disruption Substances
(EDSs) were determined in 10 sample stations in top and sub soils
seasonally. PAHs was determined the use of Varian 300 gas
chromatograph interfaced with flame ionization detector. Instruments
and reagents used are of standard and chromatographic grades
respectively. PCC and CA results showed that the classification of
PAHs along pyrolitic and petrogenic organics used in source
signature is about the predominance PAHs in environmental matrix.
Therefore, the distribution of PAHs in the studied stations revealed
the presence of trace quantities of the vast majority of the sixteen
PAHs, which may ultimately inhabit the actual source signature
authentication. Therefore, factors to be considered when evaluating
possible sources of PAHs could be; type and extent of bacterial
metabolism, transformation products/substrates, and environmental
factors such as salinity, pH, oxygen concentration, nutrients, light
intensity, temperature, co-substrates, and environmental medium are
hereby recommended as factors to be considered when evaluating
possible sources of PAHs.
Abstract: Polycyclic aromatic hydrocarbons (PAHs) are formed
during the pyrolysis of scrap tyres to produce tyre pyrolytic oil
(TPO). Due to carcinogenic, mutagenic, and toxic properties PAHs
are priority pollutants. Hence it is essential to remove PAHs from
TPO before utilising TPO as a petroleum fuel alternative (to run the
engine). Agricultural wastes have promising future to be utilized as
biosorbent due to their cost effectiveness, abundant availability, high
biosorption capacity and renewability. Various low cost adsorbents
were prepared from natural sources. Uptake of PAHs present in tyre
pyrolytic oil was investigated using various low-cost adsorbents of
natural origin including sawdust (shisham), coconut fiber, neem bark,
chitin, activated charcoal. Adsorption experiments of different PAHs
viz. naphthalene, acenaphthalene, biphenyl and anthracene have been
carried out at ambient temperature (25°C) and at pH 7. It was
observed that for any given PAH, the adsorption capacity increases
with the lignin content. Freundlich constant Kf and 1/n have been
evaluated and it was found that the adsorption isotherms of PAHs
were in agreement with a Freundlich model, while the uptake
capacity of PAHs followed the order: activated charcoal> saw dust
(shisham) > coconut fiber > chitin. The partition coefficients in
acetone-water, and the adsorption constants at equilibrium, could be
linearly correlated with octanol–water partition coefficients. It is
observed that natural adsorbents are good alternative for PAHs
removal. Sawdust of Dalbergia sissoo, a by-product of sawmills was
found to be a promising adsorbent for the removal of PAHs present in
TPO. It is observed that adsorbents studied were comparable to those
of some conventional adsorbents.
Abstract: The MIGR’HYCAR research project was initiated to provide decisional tools for risks connected to oil spill drifts in continental waters. These tools aim to serve in the decision-making process once oil spill pollution occurs and/or as reference tools to study scenarios of potential impacts of pollutions on a given site. This paper focuses on the study of the distribution of polycyclic aromatic hydrocarbons (PAHs) and derivatives from oil spill in water as function of environmental parameters. Eight petroleum oils covering a representative range of commercially available products were tested. 41 polycyclic aromatic hydrocarbons (PAHs) and derivates, among them 16 EPA priority pollutants were studied by dynamic tests at laboratory scale. The chemical profile of the water soluble fraction was different from the parent oil profile due to the various water solubility of oil components. Semi-volatile compounds (naphtalenes) constitute the major part of the water soluble fraction. A large variation in composition of the water soluble fraction was highlighted depending on oil type. Moreover, four environmental parameters (temperature, suspended solid quantity, salinity and oil: water surface ratio) were investigated with the Taguchi experimental design methodology. The results showed that oils are divided into three groups: the solubility of Domestic fuel and Jet A1 presented a high sensitivity to parameters studied, meaning they must be taken into account. For Gasoline (SP95-E10) and Diesel fuel, a medium sensitivity to parameters was observed. In fact, the four others oils have shown low sensitivity to parameters studied. Finally, three parameters were found to be significant towards the water soluble fraction.
Abstract: Some of the polycyclic aromatic hydrocarbons (PAHs)
are the strongest known carcinogens compounds; the majority of
them are mostly produced by the incomplete combustion of fossil
fuels; Motor vehicles are a significant source of polycyclic aromatic
hydrocarbon (PAH) where diesel emission is one of the main sources
of such compounds available in the ambient air. There is a big
concern about the increasing concentration of PAHs in the
environment. Researchers are trying to explore optimal methods to
reduce those pollutants and improve the quality of air. Water blended
fuel is one of the possible approaches to reduce emission of PAHs
from the combustion of diesel in urban and domestic vehicles. In this
work a modeling study was conducted using CHEMKIN-PRO
software to simulate spray combustion at similar diesel engine
conditions. Surrogate fuel of (80 % n-heptane and 20 % toluene) was
used due to detailed kinetic and thermodynamic data needed for
modeling is available for this kind of fuel but not available for diesel.
An emulsified fuel with 3, 5, 8, 10 and 20 % water by volume is used
as an engine feed for this study. The modeling results show that water
has a significant effect on reducing engine soot and PAHs precursors
formation up to certain extent.
Abstract: The pollution of sediments sampled from the North
Port by polycyclic aromatic hydrocarbons (PAHs) was investigated.
Concentrations of PAHs estimated in the port sediments ranged from
199 to 2851.2 μg/kg dw. The highest concentration was found which
is closed to the Berth line, this locations affected by intensive
shipping activities and Land based runoff and they were dominated
by the high molecular weight PAHs (4–6- rings). Source
identification showed that PAHs originated mostly from the
pyrogenic source either from the combustion of fossil fuels, grass,
wood and coal (majority of the samples). Ecological Risk Assessment
on the port sediments presented that slightly adverse ecological
effects to biological community are expected to occur at the vicinity
of the stations 1 and 4. Thus PAHs are not considered as pollutants of
concern in the North Port.