Abstract: Desalination using solar energy coupled with membrane techniques such as vacuum membrane distillation (VMD) is considered as an interesting alternative for the production of pure water. During this work, a developed model of a polytetrafluoroethylene (PTFE) hollow fiber membrane module of a VMD unit of seawater was carried out. This simulation leads to establishing a comparison between the effects of two different equations of the vaporization latent heat on the membrane surface temperature and on the unit productivity. Besides, in order to study the effect of putting membrane modules in series on the outlet fluid temperature and on the productivity of the process, a simulation was executed.
Abstract: Membrane distillation is an emerging technology which has been used to produce freshwater and purify different types of aqueous mixtures. Qatar is an arid country where almost 100% of its freshwater demand is supplied through the energy-intensive thermal desalination process. The country’s need for water has reached an all-time high which stipulates finding an alternative way to augment freshwater without adding any drastic affect to the environment. The objective of this paper was to investigate the potential of using the industrial low grade waste heat to produce freshwater using membrane distillation. The main part of this work was conducting a heat audit on selected Qatari chemical industries to estimate the amounts of freshwater produced if such industrial waste heat were to be recovered. By the end of this work, the main objective was met and the heat audit conducted on the Qatari chemical industries enabled us to estimate both the amounts of waste heat which can be potentially recovered in addition to the amounts of freshwater which can be produced if such waste heat were to be recovered.
By the end, the heat audit showed that around 605 Mega Watts of waste heat can be recovered from the studied Qatari chemical industries which resulted in a total daily production of 5078.7 cubic meter of freshwater.
This water can be used in a wide variety of applications such as human consumption or industry. The amount of produced freshwater may look small when compared to that produced through thermal desalination plants; however, one must bear in mind that this water comes from waste and can be used to supply water for small cities or remote areas which are not connected to the water grid. The idea of producing freshwater from the two widely-available wastes (thermal rejected brine and waste heat) seems promising as less environmental and economic impacts will be associated with freshwater production which may in the near future augment the conventional way of producing freshwater currently being thermal desalination. This work has shown that low grade waste heat in the chemical industries in Qatar and perhaps the rest of the world can contribute to additional production of freshwater using membrane distillation without significantly adding to the environmental impact.
Abstract: This paper presents a complete dynamic modeling
of a membrane distillation process. The model contains two
consistent dynamic models. A 2D advection-diffusion equation
for modeling the whole process and a modified heat equation
for modeling the membrane itself. The complete model describes
the temperature diffusion phenomenon across the feed, membrane,
permeate containers and boundary layers of the membrane. It gives
an online and complete temperature profile for each point in the
domain. It explains heat conduction and convection mechanisms that
take place inside the process in terms of mathematical parameters, and
justify process behavior during transient and steady state phases. The
process is monitored for any sudden change in the performance at any
instance of time. In addition, it assists maintaining production rates
as desired, and gives recommendations during membrane fabrication
stages. System performance and parameters can be optimized
and controlled using this complete dynamic model. Evolution of
membrane boundary temperature with time, vapor mass transfer along
the process, and temperature difference between membrane boundary
layers are depicted and included. Simulations were performed over
the complete model with real membrane specifications. The plots
show consistency between 2D advection-diffusion model and the
expected behavior of the systems as well as literature. Evolution
of heat inside the membrane starting from transient response till
reaching steady state response for fixed and varying times is
illustrated.
Abstract: Qatar’s primary source of fresh water is through
seawater desalination. Amongst the major processes that are
commercially available on the market, the most common large scale
techniques are Multi-Stage Flash distillation (MSF), Multi Effect
distillation (MED), and Reverse Osmosis (RO). Although commonly
used, these three processes are highly expensive down to high energy
input requirements and high operating costs allied with maintenance
and stress induced on the systems in harsh alkaline media. Beside that
cost, environmental footprint of these desalination techniques are
significant; from damaging marine eco-system, to huge land use, to
discharge of tons of GHG and huge carbon footprint.
Other less energy consuming techniques based on membrane
separation are being sought to reduce both the carbon footprint and
operating costs is membrane distillation (MD).
Emerged in 1960s, MD is an alternative technology for water
desalination attracting more attention since 1980s. MD process
involves the evaporation of a hot feed, typically below boiling point
of brine at standard conditions, by creating a water vapor pressure
difference across the porous, hydrophobic membrane. Main
advantages of MD compared to other commercially available
technologies (MSF and MED) and specially RO are reduction of
membrane and module stress due to absence of trans-membrane
pressure, less impact of contaminant fouling on distillate due to
transfer of only water vapor, utilization of low grade or waste heat
from oil and gas industries to heat up the feed up to required
temperature difference across the membrane, superior water quality,
and relatively lower capital and operating cost.
To achieve the objective of this study, state of the art flat-sheet
cross-flow DCMD bench scale unit was designed, commissioned, and
tested. The objective of this study is to analyze the characteristics and
morphology of the membrane suitable for DCMD through SEM
imaging and contact angle measurement and to study the water
quality of distillate produced by DCMD bench scale unit.
Comparison with available literature data is undertaken where
appropriate and laboratory data is used to compare a DCMD distillate
quality with that of other desalination techniques and standards.
Membrane SEM analysis showed that the PTFE membrane used
for the study has contact angle of 127º with highly porous surface
supported with less porous and bigger pore size PP membrane. Study
on the effect of feed solution (salinity) and temperature on water
quality of distillate produced from ICP and IC analysis showed that
with any salinity and different feed temperature (up to 70ºC) the
electric conductivity of distillate is less than 5 μS/cm with 99.99%
salt rejection and proved to be feasible and effective process capable
of consistently producing high quality distillate from very high feed
salinity solution (i.e. 100000 mg/L TDS) even with substantial
quality difference compared to other desalination methods such as
RO and MSF.
Abstract: Seawater desalination has been accepted as one of the most effective solutions to the growing problem of a diminishing clean drinking water supply. Currently two desalination technologies dominate the market – the thermally driven multi-stage flash distillation (MSF) and the membrane based reverse osmosis (RO). However, in recent years membrane distillation (MD) has emerged as a potential alternative to the established means of desalination. This research project intended to determine the viability of MD as an alternative process to MSF and RO for seawater desalination. Specifically the project involves conducting thermodynamic analysis of the process based on the second law of thermodynamics to determine the efficiency of the MD. Data was obtained from experiments carried out on a laboratory rig. To determine exergy values required for the exergy analysis, two separate models were built in Engineering Equation Solver – the ’Minimum Separation Work Model’ and the ‘Stream Exergy Model’. The efficiency of MD process was found to be 17.3 % and the energy consumption was determined to be 4.5 kWh to produce one cubic meter of fresh water. The results indicate MD has potential as a technique for seawater desalination compared to RO and MSF. However it was shown that this was only the case if an alternate energy source such as green or waste energy was available to provide the thermal energy input to the process. If the process was required to power itself, it was shown to be highly inefficient and in no way thermodynamically viable as a commercial desalination process.
Abstract: Membrane distillation (MD) is a rising technology for
seawater or brine desalination process. In this work, an air gap
membrane distillation (AGMD) performance was investigated for
aqueous NaCl solution along with natural ground water and seawater.
In order to enhance the performance of the AGMD process in
desalination, that is, to get more flux, it is necessary to study the
effect of operating parameters on the yield of distillate water. The
influence of operational parameters such as feed flow rate, feed
temperature, feed salt concentration, coolant temperature and air gap
thickness on the membrane distillation (MD) permeation flux have
been investigated for low and high salt solution. the natural
application of ground water and seawater over 90 h continuous
operation, scale deposits observed on the membrane surface and
reduction in flux represents 23% for ground water and 60% for
seawater, in 90 h. This reduction was eliminated (less than 14 %) by
acidification of feed water. Hence, promote the research attention in
apply of AGMD for the ground water as well as seawater
desalination over today-s conventional RO operation.
Abstract: The possibility of producing drinking water from
brackish ground water using Vacuum membrane distillation (VMD)
process was studied. It is a rising technology for seawater or brine
desalination process. The process simply consists of a flat sheet
hydrophobic micro porous PTFE membrane and diaphragm vacuum
pump without a condenser for the water recovery or trap. In this
work, VMD performance was investigated for aqueous NaCl solution
and natural ground water. The influence of operational parameters
such as feed flow rate (30 to 55 l/h), feed temperature (313 to 333 K),
feed salt concentration (5000 to 7000 mg/l) and permeate pressure
(1.5 to 6 kPa) on the membrane distillation (MD) permeation flux
have been investigated. The maximum flux reached to 28.34 kg/m2 h
at feed temperature, 333 K; vacuum pressure, 1.5 kPa; feed flow rate,
55 l/h and feed salt concentration, 7000 mg/l. The negligible effects
in the reduction of permeate flux found over 150 h experimental run
for salt water. But for the natural ground water application over 75 h,
scale deposits observed on the membrane surface and 29% reduction
in the permeate flux over 75 h. This reduction can be eliminated by
acidification of feed water. Hence, promote the research attention in
apply of VMD for the ground water purification over today-s
conventional RO operation.
Abstract: Vacuum membrane distillation (VMD) process can be
used for water purification or the desalination of salt water. The
process simply consists of a flat sheet hydrophobic micro porous
PTFE membrane and diaphragm vacuum pump without a condenser
for the water recovery or trap. The feed was used aqueous NaCl
solution. The VMD experiments were performed to evaluate the heat
and mass transfer coefficient of the boundary layer in a membrane
module. The only operating parameters are feed inlet temperature,
and feed flow rate were investigated. The permeate flux was strongly
affected by the feed inlet temperature, feed flow rate, and boundary
layer heat transfer coefficient. Since lowering the temperature
polarization coefficient is essential enhance the process performance
considerable and maximizing the heat transfer coefficient for
maximizes the mass flux of distillate water. In this paper, the results
of VMD experiments are used to measure the boundary layer heat
transfer coefficient, and the experimental results are used to reevaluate
the empirical constants in the Dittus- Boelter equation.
Abstract: Computational fluid dynamics (CFD) simulations
carried out in this paper show that spacer orientation has a major
influence on temperature patterns and on the heat transfer rates. The
local heat flux values significantly vary from high to very low values
at each filament when spacer touches the membrane surface. The
heat flux profile is more uniform when spacer filaments are not in
contact with the membrane thus making this arrangement more
beneficial. The temperature polarization is also found to be less in
this case when compared to the empty channel.
Abstract: In this work Membrane Distillation is applied to
concentrate orange Juice. Clarified orange juice (11o Brix) obtained
from fresh fruits and a sugar solution was subjected to membrane
distillation. The experiments were performed on a flat sheet module
using orange juice and sucrose solution as feeds. The concentration
of a sucrose solution, used as a model fruit juice and also orange
juice, was carried out in a direct contact membrane distillation using
hydrophobic PTFE membrane of pore size 0.2 μm and porosity 70%.
Surface modification of PTFE membrane has been carried out by
treating membrane with alcohol and water solution to make it
hydrophilic and then hydrophobicity was regained by drying. The
influences of the feed temperature, feed concentration, flow rate,
operating time on the permeate flux were studied for treated and non
treated membrane. In this work treated and non treated membrane
were compared in terms of water flux, Within the tested range, MD
with surface modified membrane the water flux has been
significantly improved by treating the membrane surface.