Abstract: Carbon dioxide has been well associated with greenhouse effect, and due to its corrosive nature it is an undesirable compound. A variety of physical-chemical processes are available for the removal of carbon dioxide. Previous attempts in this field have established alkanolamine group has the capability to remove carbon dioxide. So, this study combined the polymeric membrane and alkanolamine solutions to fabricate the amine polymeric membrane (APM) to remove carbon dioxide (CO2). This study entails the effect of three types of amines, monoethanolamine (MEA), diethanolamine (DEA), and methyldiethanolamine (MDEA). The effect of each alkanolamine group on the morphology and performance of polyether sulfone (PES) polymeric membranes was studied. Flat sheet membranes were fabricated by solvent evaporation method by adding polymer and different alkanolamine solutions in the N-Methyl-2-pyrrolidone (NMP) solvent. The final membranes were characterized by using Field Emission Electron Microscope (FESEM), Fourier Transform Infrared (FTIR), and Thermo-Gravimetric Analysis (TGA). The membrane separation performance was studied. The PES-DEA and PES-MDEA membrane has good ability to remove carbon dioxide.
Abstract: This work presents a theoretical investigation of the
simultaneous absorption of CO2 and H2S into aqueous solutions of
MDEA and DEA. In this process the acid components react
with the basic alkanolamine solution via an exothermic,
reversible reaction in a gas/liquid absorber. The use of amine
solvents for gas sweetening has been investigated using
process simulation programs called HYSYS and ASPEN. We
use Electrolyte NRTL and Amine Package and Amines
(experimental) equation of state. The effects of temperature and
circulation rate and amine concentration and packed column and
murphree efficiency on the rate of absorption were studied.
When lean amine flow and concentration increase, CO2 and H2S
absorption increase too. With the improvement of inlet amine
temperature in absorber, CO2 and H2S penetrate to upper stages of
absorber and absorption of acid gases in absorber decreases. The CO2
concentration in the clean gas can be greatly influenced by the
packing height, whereas for the H2S concentration in the clean gas the
packing height plays a minor role. HYSYS software can not
estimate murphree efficiency correctly and it applies the same
contributions in all diagrams for HYSYS software. By
improvement in murphree efficiency, maximum temperature
of absorber decrease and the location of reaction transfer to the
stages of bottoms absorber and the absorption of acid gases
increase.