Abstract: In this preliminary work, locally available husk of Cajanus cajan (commonly known in India as Tur or Arhar), a bio-waste, has been used in its physically treated and chemically activated form for the removal of binary Cu (II) and Zn(II) ions from the real waste water obtained from an electroplating industry in Bangalore, Karnataka, India and from laboratory prepared binary solutions having almost similar composition of the metal ions, for comparison. The real wastewater after filtration and dilution for five times was used for biosorption studies at the normal pH of the solutions at room temperature. Langmuir's binary model was used to calculate the metal uptake capacities of the biosorbents. It was observed that Cu(II) is more competitive than Zn(II) in biosorption. In individual metal biosorption, Cu(II) uptake was found to be more than that of the Zn(II) and a similar trend was observed in the binary metal biosorption from real wastewater and laboratory prepared solutions. FTIR analysis was carried out to identify the functional groups in the industrial wastewater and EDAX for the elemental analysis of the biosorbents after experiments.
Abstract: Evaluation of dynamic earth pressure on retaining wall is a topic of primary importance. In present paper, dynamic active earth pressure and displacement of flexible cantilever retaining wall has been evaluated analytically using 2-DOF mass-spring-dashpot model by incorporating both wall and backfill properties. The effect of wall flexibility on dynamic active earth pressure and wall displacement are studied and presented in graphical form. The obtained results are then compared with the various conventional methods, experimental analysis and also with PLAXIS analysis. It is observed that the dynamic active earth pressure decreases with increase in the wall flexibility while wall displacement increases linearly with flexibility of the wall. The results obtained by proposed 2-DOF analytical model are found to be more realistic and economical.
Abstract: Chromium in the environment is considered as one of the most toxic elements probably next only to mercury and arsenic. It is acutely toxic, mutagenic and carcinogenic in the environment. Chromium contamination of soil and underground water due to industrial activities is a very serious problem in several parts of India covering Karnataka, Tamil Nadu, Andhra Pradesh etc. Functionally modified Activated Carbon Fabrics (ACF) offer targeted chromium removal from drinking water and industrial effluents. Activated carbon fabric is a light weight adsorbing material with high surface area and low resistance to fluid flow. We have investigated surface modification of ACF using various acids in the laboratory through batch as well as through continuous flow column experiments with a view to develop the optimum conditions for chromium removal. Among the various acids investigated, phosphoric acid modified ACF gave best results with a removal efficiency of 95% under optimum conditions. Optimum pH was around 2 – 4 with 2 hours contact time. Continuous column experiments with an effective bed contact time (EBCT) of 5 minutes indicated that breakthrough occurred after 300 bed volumes. Adsorption data followed a Freundlich isotherm pattern. Nickel adsorbs preferentially and sulphate reduces chromium adsorption by 50%. The ACF could be regenerated up to 52.3% using 3 M NaOH under optimal conditions. The process is simple, economical, energy efficient and applicable to industrial effluents and drinking water.
Abstract: The interest in air conditioning using renewable energies is increasing. The thermal energy produced from the solar energy can be converted to useful cooling and heating through the thermochemical or thermophysical processes by using thermally activated energy conversion systems. The ambient air contains so much water that very high dehumidification rates are required. For a continuous dehumidification of the process air, the water adsorbed on the desiccant material has to be removed, which is done by allowing hot air to flow through the desiccant material (regeneration). A solid desiccant cooling system transfers moisture from the inlet air to the silica gel by using two processes: Absorption process and the regeneration process. The main aim of this paper is to study how the dehumidification rate, the generation temperature and many other factors influence the efficiency of a solid desiccant system by using TRNSYS software. The results show that the desiccant system could be used to decrease the humidity rate of the entering air.
Abstract: The major environmental risk of soil pollution is the
contamination of groundwater by infiltration of organic and inorganic
pollutants which can cause a serious menace. To prevent this risk and
to protect the groundwater, we proceeded in this study to test the
reliability of a biosolid as barrier to prevent the migration of very
dangerous pollutants as ‘Cadmium’ through the different soil layers. In this study, we tried to highlight the effect of several parameters
such as: turbidity (different cycle of Hydration/Dehydration),
rainfall, effect of initial Cd(II) concentration and the type of soil.
These parameters allow us to find the most effective manner to
integrate this barrier in the soil. From the results obtained, we found a
significant effect of the barrier. Indeed, the recorded passing
quantities are lowest for the highest rainfall; we noted also that the
barrier has a better affinity towards higher concentrations; the most
retained amounts of cadmium has been in the top layer of the two
types of soil tested, while the lowest amounts of cadmium are
recorded in the bottom layers of soils.
Abstract: This study aims at improving the urban hydrological
cycle of the Orléans agglomeration (France) and understanding the
relationship between physical and chemical parameters of urban
surface runoff and the hydrological conditions. In particular water
quality parameters such as pH, conductivity, total dissolved solids,
major dissolved cations and anions, and chemical and biological
oxygen demands were monitored for three types of urban water
discharges (wastewater treatment plant output (WWTP), storm
overflow and stormwater outfall) under two hydrologic scenarios (dry
and wet weather). The first results were obtained over a period of five
months. Each investigated (Ormes, l’Egoutier and La Corne) outfall
represents an urban runoff source that receives water from runoff
roads, gutters, the irrigation of gardens and other sources of flow over
the Earth’s surface that drains in its catchments and carries it to the
Loire River. In wet weather conditions there is rain water runoff and
an additional input from the roof gutters that have entered the
stormwater system during rainfall. For the comparison the results La
Chilesse is a storm overflow that was selected in our study as a
potential source of waste water which is located before the (WWTP). The comparison of the physical-chemical parameters (total
dissolved solids, turbidity, pH, conductivity, dissolved organic
carbon (DOC), concentration of major cations and anions) together
with the chemical oxygen demand (COD) and biological oxygen
demand (BOD) helped to characterize sources of runoff waters in the
different watersheds. It also helped to highlight the infiltration of
wastewater in some stormwater systems that reject directly in the
Loire River. The values of the conductivity measured in the outflow
of Ormes were always higher than those measured in the other two
outlets. The results showed a temporal variation for the Ormes outfall
of conductivity from 1465 μS cm-1 in the dry weather flow to 650 μS
cm-1 in the wet weather flow and also a spatial variation in the wet
weather flow from 650 μS cm-1 in the Ormes outfall to 281 μS cm-1
in L’Egouttier outfall. The ultimate BOD (BOD28) showed a
significant decrease in La Corne outfall from 181 mg L-1 in the wet
weather flow to 95 mg L-1 in the dry weather flow because of the
nutrient load that was transported by the runoff.
Abstract: Different countries have introduced different schemes
and policies to counter global warming. The rationale behind the
proposed policies and the potential barriers to successful
implementation of the policies adopted by the countries were
analyzed and estimated based on different models. It is argued that
these models enhance the transparency and provide a better
understanding to the policy makers. However, these models are
underpinned with several structural and baseline assumptions. These
assumptions, modeling features and future prediction of emission
reductions and other implication such as cost and benefits of a
transition to a low-carbon economy and its economy wide impacts
were discussed. On the other hand, there are potential barriers in the
form political, financial, and cultural and many others that pose a
threat to the mitigation options.
Abstract: This study was undertaken at four different sites
(north polluted, south polluted, south healthy and north healthy) in
Tehran, in order to examine whether there was a relationship between
publicly available air quality data and the public’s perception of air
quality and to suggest some guidelines for reducing air pollution. A
total of 200 people were accidentally filled out the research
questionnaires at mentioned sites and air quality data were obtained
simultaneously from the Air Quality Control Department. Data was
analyzed in Excel and SPSS software’s. Clean air and job security
were of great importance to people comparing to other pleasant
aspect of life. Also air pollution and serious diseases were the most
important of people concerns. Street monitors and news paper
services on air quality were little used by the public as a means of
obtaining information on air pollution. Using public transportation
and avoiding inevitable journeys are the most important ways for
reducing air pollution. The results reveal that the public’s perception
of air quality is not a reliable indicator of the actual levels of air
pollution.
Abstract: The present study aims to investigate the performance
of Moringa oleifera seed extract as natural coagulant in clarification
of secondary wastewater treatment plant (MWWTP) located in East
of Algiers, Algeria. Coagulation flocculation performance of
Moringa oleifera was evaluated through supernatant residual
turbidity after jar test trials. Various influence parameters namely
Moringa oleifera dosage and pH have been considered. Tests on
Reghaia wastewater, having 129 NTU of initial turbidity, showed a
removal of 69.45% of residual turbidity with only 1.5 mg/l of
Moringa oleifera. This sufficient removal capability encourages the
use of this bioflocculant for treatment of turbid waters. Indeed,
Moringa oleifera which is a natural resource available locally (South
of Algeria) coupled to the non-toxicity, biocompatibility and
biodegradability, may be a very interesting alternative to the
conventional coagulants used so far.
Abstract: The current paper presents an extensive bottom-up
framework for assessing building sector-specific vulnerability to
climate change: energy supply and demand. The research focuses on
the application of downscaled seasonal models for estimating energy
performance of buildings in Greece. The ARW-WRF model has
been set-up and suitably parameterized to produce downscaled
climatological fields for Greece, forced by the output of the CFSv2
model. The outer domain, D01/Europe, included 345 x 345 cells of
horizontal resolution 20 x 20 km2 and the inner domain, D02/Greece,
comprised 180 x 180 cells of 5 x 5 km2 horizontal resolution. The
model run has been setup for a period with a forecast horizon of 6
months, storing outputs on a six hourly basis.
Abstract: The goal of this experiment is to evaluate the
effectiveness of different leachate pre-treatment options in terms of
COD and ammonia removal. This research focused on the evaluation
of physical-chemical methods for pre-treatment of leachate that
would be effective and rapid in order to satisfy the requirements of
the sewer discharge by-laws. The four pre-treatment options
evaluated were: air stripping, chemical coagulation, electrocoagulation
and advanced oxidation with sodium ferrate. Chemical
coagulation reported the best COD removal rate at 43%, compared to
18% for both air stripping and electro-coagulation, and 20% for
oxidation with sodium ferrate. On the other hand, air stripping was
far superior to the other treatment options in terms of ammonia
removal with 86%. Oxidation with sodium ferrate reached only 16%,
while chemical coagulation and electro-coagulation removed less
than 10%. When combined, air stripping and chemical coagulation
removed up to 50% COD and 85% ammonia.
Abstract: The main objective of this study was to assess the
seasonal variation of atmospheric polycyclic aromatic hydrocarbon
(PAH) concentrations associated with PM10 in an urban site of Győr,
Hungary. A total of 112 PM10 aerosol samples were collected in the
years of 2012 and 2013 and analyzed for PAHs by gas
chromatography method. The total PAH concentrations (sum of the
concentrations of 19 individual PAH compounds) ranged from 0.19
to 70.16 ng/m3 with the mean value of 12.29 ng/m3. Higher
concentrations of both total PAHs and benzo[a]pyrene (BaP) were
detected in samples collected in the heating seasons. Using BaPequivalent
potency index on the carcinogenic PAH concentration
data, the local population appears to be exposed to significantly
higher cancer risk in the heating seasons. However, the comparison
of the BaP and total PAH concentrations observed for Győr with
other cities it was found that the PAH levels in Győr generally
corresponded to the EU average.
Abstract: Evapotranspiration is one of the most important
components of the hydrological cycle. Evapotranspiration (ETo) is an
important variable in water and energy balances on the earth’s
surface, and knowledge of the distribution of ET is a key factor in
hydrology, climatology, agronomy and ecology studies. Many
researchers have a valid relationship, which is a function of climate
factors, to estimate the potential evapotranspiration presented to the
plant water stress or water loss, prevent. The FAO-Penman method
(PM) had been recommended as a standard method. This method
requires many data and these data are not available in every area of
world. So, other methods should be evaluated for these conditions.
When sufficient or reliable data to solve the PM equation are not
available then Hargreaves equation can be used. The Hargreaves
equation (HG) requires only daily mean, maximum and minimum air
temperature extraterrestrial radiation .In this study, Hargreaves
method (HG) were evaluated in 12 stations in the North West region
of Iran. Results of HG and M.HG methods were compared with
results of PM method. Statistical analysis of this comparison showed
that calibration process has had significant effect on efficiency of
Hargreaves method.
Abstract: To solve these problems, we investigated the management system of heating enterprise, including strategic planning based on the balanced scorecard (BSC), quality management in accordance with the standards of the Quality Management System (QMS) ISO 9001 and analysis of the system based on expert judgment using fuzzy inference. To carry out our work we used the theory of fuzzy sets, the QMS in accordance with ISO 9001, BSC, method of construction of business processes according to the notation IDEF0, theory of modeling using Matlab software simulation tools and graphical programming LabVIEW. The results of the work are as follows: We determined possibilities of improving the management of heat-supply plant-based on QMS; after the justification and adaptation of software tool it has been used to automate a series of functions for the management and reduction of resources and for the maintenance of the system up to date; an application for the analysis of the QMS based on fuzzy inference has been created with novel organization of communication software with the application enabling the analysis of relevant data of enterprise management system.
Abstract: The objective of this study is to conduct computational
fluid dynamic (CFD) simulations for evaluating the cooling efficacy
from vegetation implanted in a public park in the Taipei, Taiwan. To
probe the impacts of park renewal by means of adding three pavilions
and supplementary green areas on urban microclimates, the simulated
results have revealed that the park having a higher percentage of green
coverage ratio (GCR) tended to experience a better cooling effect.
These findings can be used to explore the effects of different greening
modifications on urban environments for achieving an effective
thermal comfort in urban public spaces.
Abstract: This paper addresses the design of hospital Intensive
Care Unit windows for the achievement of visual comfort and energy
savings. The aim was to identify the window size and shading system
configurations that could fulfill daylighting adequacy, avoid glare
and reduce energy consumption. The study focused on addressing the
effect of utilizing different shading systems in association with a
range of Window-to-Wall Ratios (WWR) in different orientations
under the desert clear-sky of Cairo, Egypt.
The results of this study demonstrated that solar penetration is a
critical concern affecting the design of ICU windows in desert
locations, as in Cairo, Egypt. Use of shading systems was found to be
essential in providing acceptable daylight performance and energy
saving. Careful positioning of the ICU window towards a proper
orientation can dramatically improve performance. It was observed
that ICU windows facing the north direction enjoyed the widest range
of successful window configuration possibilities at different WWRs.
ICU windows facing south enjoyed a reasonable number of
configuration options as well. By contrast, the ICU windows facing
the east orientation had a very limited number of options that provide
acceptable performance. These require additional local shading
measures at certain times due to glare incidence. Moreover, use of
horizontal sun breakers and solar screens to protect the ICU windows
proved to be more successful than the other alternatives in a wide
range of Window to Wall Ratios. By contrast, the use of light shelves
and vertical shading devices seemed questionable.
Abstract: Intermetallic materials are among advanced
technology materials that have outstanding mechanical and physical
properties for high temperature applications. Especially creep
resistance, low density and high hardness properties stand out in such
intermetallics. The microstructure, mechanical properties of %88Ni-
%10Cr and %2Mn powders were investigated using specimens
produced by tube furnace sintering at 900-1300°C temperature. A
composite consisting of ternary additions, a metallic phase, Fe, Cr
and Mn have been prepared under Ar shroud and then tube furnace
sintered. XRD, SEM (Scanning Electron Microscope), were
investigated to characterize the properties of the specimens.
Experimental results carried out for composition %88Ni-%10Cr and
%2Mn at 1300°C suggest that the best properties as 138,80HV and
6,269/cm3 density were obtained at 1300°C.
Abstract: Through use of novel modern/rapid processing
techniques such as screen printing and Near-Infrared (NIR) radiative
curing, process time for the sintering of sintered nickel plaques,
applicable to alkaline nickel battery chemistries, has been drastically
reduced from in excess of 200 minutes with conventional convection
methods to below 2 minutes using NIR curing methods. Steps have
also been taken to remove the need for forming gas as a reducing
agent by implementing carbon as an in-situ reducing agent, within the
ink formulation.
Abstract: An important problem for the CaSO4/CaSO4・1/2H2O
Chemical heat pump (CHP) is that the material is deactivated through
repetitive reaction between hydration and dehydration in which the
crystal phase of the material is transformed from III-CaSO4 to
II-CaSO4. We investigated suppression on the phase change by adding
a sulfated compound. The most effective material was MgSO4. MgSO4
doping increased the durability of CaSO4 in the actual CHP repetitive
cycle of hydration/dehydration to 3.6 times that of undoped CaSO4.
The MgSO4-doped CaSO4 showed a higher phase transition
temperature and activation energy for crystal transformation from
III-CaSO4 to II-CaSO4. MgSO4 doping decreased the crystal lattice
size of CaSO4・1/2H2O and II-CaSO4 to smaller than that of undoped
CaSO4. Modification of the crystal structure is considered to be related
to the durability change in CaSO4 resulting from MgSO4 doping.
Abstract: Super steel materials play a vital role in the
construction and fabrication of structural, piping and pipeline
components. In assuring the integrity of onshore and offshore
operating systems, they enable life cycle costs to be minimized. In
this context, Duplex stainless steel (DSS) material related welding on
constructions and fabrications plays a significant role in maintaining
and assuring integrity at an optimal expenditure over the life cycle of
production and process systems as well as associated structures. In
DSS welding, factors such as gap geometry, shielding gas supply
rate, welding current, and type of the welding process are vital to the
final joint performance. Hence, an experimental investigation has
been performed using an engineering robust design approach
(ERDA) to investigate the optimal settings that generate optimal
super DSS (i.e. UNS S32750) joint performance. This manuscript
illustrates the mathematical approach and experimental design,
optimal parameter settings and results of the verification experiment.