Abstract: Rivers have transient storage or dead zones where
injected pollutants or solutes are entrapped for considerable period of
time, known as residence time, before being released into the main
flowing zones of rivers. In this study, a new empirical expression for
residence time, implementing genetic programming on published
dispersion data, has been derived. The proposed expression uses few
hydraulic and geometric characteristics of rivers which are normally
known to the authorities. When compared with some reported
expressions, based on various statistical indices, it can be concluded
that the proposed expression predicts the residence time of pollutants
in natural rivers more accurately.
Abstract: The capability of exploiting the electronic charge and
spin properties simultaneously in a single material has made diluted
magnetic semiconductors (DMS) remarkable in the field of
spintronics. We report the designing of DMS based on zinc-blend
ZnO doped with Cr impurity. The full potential linearized augmented
plane wave plus local orbital FP-L(APW+lo) method in density
functional theory (DFT) has been adapted to carry out these
investigations. For treatment of exchange and correlation energy,
generalized gradient approximations have been used. Introducing Cr
atoms in the matrix of ZnO has induced strong magnetic moment
with ferromagnetic ordering at stable ground state. Cr:ZnO was found
to favor the short range magnetic interaction that
reflect tendency of Cr clustering. The electronic structure of ZnO is
strongly influenced in the presence of Cr impurity atoms where
impurity bands appear in the band gap.
Abstract: Forward Osmosis (FO) polyamide thin-film composite
membranes have been prepared by interfacial polymerization using
commercial UF polyethersulfoneas membrane support. Different
interfacial polymerization times (10s, 30s and 60s) in the organic
solution containing trimesoyl chloride (TMC) at constant m-phenylenediamine
(MPD) concentration (2% w/v) were studied. The
synthesized polyamide membranes then tested for treatment of
natural organic matter (NOM) and compared to commercial Cellulose
TriAcetate (CTA) membrane. It was found that membrane prepared
with higher reaction time (30s and 60s) exhibited better membrane
performance (flux and humic acid removal) over commercial CTA
membrane.
Abstract: Depositional environment and source potential of the
different organic-rich levels of Devonian age (up to 990m thick) from
the onshore EC-1 well (Southern Tunisia) were investigated based on
the analysis of more than 130 cutting samples by different
geochemical techniques (Rock-Eval pyrolysis, GC-MS). The
obtained results including Rock Eval Pyrolysis data and biomarker
distribution (terpanes, steranes and aromatics) have been used to
describe the depositional environment and to assess the thermal
maturity of the Devonian organic matter. These results show that the
Emsian deposits exhibit poor to fair TOC contents. The associated
organic matter is composed of mixed kerogen (type II/III), as
indicated by the predominance of C29 steranes over C27 and C28
homologous, that was deposited in a slightly reduced environment
favoring organic matter preservation. Thermal maturity assessed from
Tmax, TNR and MPI-1 values shows a mature stage of organic
matter. The Middle Devonian (Eifelian) shales are rich in type II
organic matter that was deposited in an open marine depositional
environment. The TOC values are high and vary between 2 and 7%
indicating good to excellent source rock. The relatively high HI
values (reaching 547 mg HC/g TOC) and the low values of t19/t23
tricyclic terpane ratio (< 0.2) confirm the marine origin of the organic
matter (type II). During the Upper Devonian, the organic matter was
deposited under variable redox conditions, oxic to suboxic which is
clearly indicated by the low C35/C34 hopanes ratio, immature to
marginally mature with the vitrinite reflectance ranging from 0.5 to
0.7 Ro and Tmax value of 426°C-436 °C and the TOC values range
between 0.8% to 4%.
Abstract: This paper presents effects of distilled water, seawater
and sustained bending strains of 30% and 50% ultimate strain at
room temperature, on the durability of unidirectional pultruded
carbon fiber reinforced polymer (CFRP) plates. In this study,
dynamic mechanical analyzer (DMA) was used to investigate the
synergic effects of the immersions and bending strains on the viscoelastic
properties of (CFRP) such as storage modulus, tan delta and
glass transition temperature. The study reveals that the storage
modulus and glass transition temperature increase while tan delta
peak decreases in the initial stage of both immersions due to the
progression of curing. The storage modulus and Tg subsequently
decrease and tan delta increases due to the matrix plasticization. The
blister induced damages in the unstrained seawater samples enhance
water uptake and cause more serious degradation of Tg and storage
modulus than in water immersion. Increasing sustained bending
decreases Tg and storage modulus in a long run for both immersions
due to resin matrix cracking and debonding. The combined effects of
immersions and strains are not clearly reflected due to the statistical
effects of DMA sample sizes and competing processes of molecular
reorientation and postcuring.
Abstract: It is well known that in recent years magnetic
materials have received increased attention due to their properties.
For this reason a significant number of patents that were published
during the last decade are oriented towards synthesis and study of
such materials. The aim of this work is to create and study ferrite
nanocrystalline materials with spinel structure, using sol-gel
technology with participation of auto-combustion. This method is
perspective in that it is a cheap and low-temperature technique that
allows for the fine control on the product’s chemical composition.
Abstract: In the present work, the dielectric properties of
Epoxy/MWCNT-muscovite HYBRID and MIXED composites based
on a ratio 30:70 were studied. The multi-wall carbon nanotubes
(MWCNT) were prepared using two methods: (a) MWCNTmuscovite
hybrids were synthesised by chemical vapour deposition
(CVD) and (b) physically mixing muscovite with MWCNT. The
effects of different preparation of the composites and filler loading
were evaluated. It was revealed that the dielectric constants of
HYBRID epoxy composites are slightly higher than MIXED epoxy
composites. It was also indicated that the dielectric constant increased
by increasing the MWCNT filler loading.
Abstract: This work is undertaken to develop a methodology to enhance the management of dredged marine and river sediments in the North of France. The main objective of this study is to determine the main characteristics of these sediments. In this order, physical, mineralogical and chemical properties of both types of sediments are measured. Moreover, their potential impacts on the environment are assessed throughout leaching tests. From the obtained results, the potential of their use in road engineering is discussed.
Abstract: This paper presents powerful techniques for the
development of a new monitoring method based on multi-scale
entropy (MSE) in order to characterize the behaviour of the
concentrations of different gases present in the synthesis of Ammonia
and soft-sensor based on Principal Component Analysis (PCA).
Abstract: Natural hydrocarbon seepage has helped petroleum
exploration as a direct indicator of gas and/or oil subsurface
accumulations. Surface macro-seeps are generally an indication of a
fault in an active Petroleum Seepage System belonging to a Total
Petroleum System. This paper describes a case study in which
multiple analytical techniques were used to identify and characterize
trace petroleum-related hydrocarbons and other volatile organic
compounds in groundwater samples collected from Sousse aquifer
(Central Tunisia). The analytical techniques used for analyses of
water samples included gas chromatography-mass spectrometry (GCMS),
capillary GC with flame-ionization detection, Compound
Specific Isotope Analysis, Rock Eval Pyrolysis. The objective of the
study was to confirm the presence of gasoline and other petroleum
products or other volatile organic pollutants in those samples in order
to assess the respective implication of each of the potentially
responsible parties to the contamination of the aquifer. In addition,
the degree of contamination at different depths in the aquifer was also
of interest. The oil and gas seeps have been investigated using
biomarker and stable carbon isotope analyses to perform oil-oil and
oil-source rock correlations. The seepage gases are characterized by
high CH4 content, very low δ13CCH4 values (-71,9 ‰) and high
C1/C1–5 ratios (0.95–1.0), light deuterium–hydrogen isotope ratios (-
198 ‰) and light δ13CC2 and δ13CCO2 values (-23,8‰ and-23,8‰
respectively) indicating a thermogenic origin with the contribution of
the biogenic gas. An organic geochemistry study was carried out on
the more ten oil seep samples. This study includes light hydrocarbon
and biomarkers analyses (hopanes, steranes, n-alkanes, acyclic
isoprenoids, and aromatic steroids) using GC and GC-MS. The
studied samples show at least two distinct families, suggesting two
different types of crude oil origins: the first oil seeps appears to be
highly mature, showing evidence of chemical and/or biological
degradation and was derived from a clay-rich source rock deposited
in suboxic conditions. It has been sourced mainly by the lower
Fahdene (Albian) source rocks. The second oil seeps was derived
from a carbonate-rich source rock deposited in anoxic conditions,
well correlated with the Bahloul (Cenomanian-Turonian) source rock.
Abstract: Generally the natural environment is made up of air,
water and soil. The release of emission of industrial waste into
anyone of the components of the environment causes pollution.
Industrial pollution significantly threatens the inherent right of
people, to the enjoyment of a safe and secure environment. The aim
of this paper is to assess the effect of environmental pollution and
health risks of residents living near Ewekoro cement factory. The
research made use of IKONOS imagery for Geographical
Information System (GIS) to buffer and extract buildings that are less
than 1km to the factory, within 1km to 5km and above 5km to the
factory. Also questionnaire was used to elicit information on the
socio-economic factors, effect of environmental pollution on
residents and measures adopted to control industrial pollution on the
residents. Findings show that most buildings that fall between less
than 1km and 1km to 5km to the factory have high health risk in the
study area. The study recommended total relocation for the residents
of the study area to reduce health risk problems.
Abstract: The Standard Penetration Test (SPT) is the most
common in situ test for soil investigations. On the other hand, the
Cone Penetration Test (CPT) is considered one of the best
investigation tools. Due to the fast and accurate results that can be
obtained it complaints the SPT in many applications like field
explorations, design parameters, and quality control assessments.
Many soil index and engineering properties have been correlated to
both of SPT and CPT. Various foundation design methods were
developed based on the outcome of these tests. Therefore it is vital to
correlate these tests to each other so that either one of the tests can be
used in the absence of the other, especially for preliminary evaluation
and design purposes.
The primary purpose of this study was to investigate the
relationships between the SPT and CPT for different type of sandy
soils in Florida. Data for this research were collected from number of
projects sponsored by the Florida Department of Transportation
(FDOT), six sites served as the subject of SPT-CPT correlations. The
correlations were established between the cone resistance (qc), sleeve
friction (fs) and the uncorrected SPT blow counts (N) for various
soils.
A positive linear relationship was found between qc, fs and N for
various sandy soils. In general, qc versus N showed higher
correlation coefficients than fs versus N. qc/N ratios were developed
for different soil types and compared to literature values, the results
of this research revealed higher ratios than literature values.
Abstract: The aim of this paper is to give an assessment of
environmental effects of IPPC permit conditions of installations that
are in specific territory with high concentration of industrial
activities.
The IPPC permit is the permit that each operator should hold to
operate the installation as stated by the directive 2010/75/UE on
industrial emissions (integrated pollution prevention and control),
known as IED (Industrial Emissions Directive).
The IPPC permit includes all the measures necessary to achieve a
high level of protection of the environment as a whole, also defining
the monitoring requirements as measurement methodology,
frequency and evaluation procedure. The emissions monitoring of a
specific plant may also give indications of the contribution of these
emissions on the air quality of a definite area.
So, it is clear that the IPPC permits are important tools both to
improve the environmental framework and to achieve the air quality
standards, assisting to assess the possible industrial sources
contributions to air pollution.
Abstract: The present paper summarizes the analysis of the
request for consultation of information and data on industrial
emissions made publicly available on the web site of the Ministry of
Environment, Land and Sea on integrated pollution prevention and
control from large industrial installations, the so called “AIA Portal”.
As a matter of fact, a huge amount of information on national
industrial plants is already available on internet, although it is usually
proposed as textual documentation or images.
Thus, it is not possible to access all the relevant information
through interoperability systems and also to retrieval relevant
information for decision making purposes as well as rising of
awareness on environmental issue.
Moreover, since in Italy the number of institutional and private
subjects involved in the management of the public information on
industrial emissions is substantial, the access to the information is
provided on internet web sites according to different criteria; thus, at
present it is not structurally homogeneous and comparable.
To overcome the mentioned difficulties in the case of the
Coordinating Committee for the implementation of the Agreement
for the industrial area in Taranto and Statte, operating before the
IPPC permit granting procedures of the relevant installation located
in the area, a big effort was devoted to elaborate and to validate data
and information on characterization of soil, ground water aquifer and
coastal sea at disposal of different subjects to derive a global
perspective for decision making purposes. Thus, the present paper
also focuses on main outcomes matured during such experience.
Abstract: Different tools and technologies were implemented
for Crisis Response and Management (CRM) which is generally
using available network infrastructure for information exchange.
Depending on type of disaster or crisis, network infrastructure could
be affected and it could not be able to provide reliable connectivity.
Thus any tool or technology that depends on the connectivity could
not be able to fulfill its functionalities. As a solution, a new message
exchange framework has been developed. Framework provides
offline/online information exchange platform for CRM Information
Systems (CRMIS) and it uses XML compression and packet
prioritization algorithms and is based on open source web
technologies. By introducing offline capabilities to the web
technologies, framework will be able to perform message exchange
on unreliable networks. The experiments done on the simulation
environment provide promising results on low bandwidth networks
(56kbps and 28.8 kbps) with up to 50% packet loss and the solution is
to successfully transfer all the information on these low quality
networks where the traditional 2 and 3 tier applications failed.
Abstract: Kazakhstan is currently one of the dynamically
developing states in its region. The stable growth in all sectors of the
economy leads to a corresponding increase in energy consumption.
Thus country consumes significant amount of energy due to the high
level of industrialisation and the presence of energy-intensive
manufacturing such as mining and metallurgy which in turn leads to
low energy efficiency. With allowance for this the Government has
set several priorities to adopt a transition of Republic of Kazakhstan
to a “green economy”. This article provides an overview of
Kazakhstan’s energy efficiency situation in for the period of 1991-
2014. First, the dynamics of production and consumption of
conventional energy resources are given. Second, the potential of
renewable energy sources is summarised followed by the description
of GHG emissions trends in the country. Third, Kazakhstan’ national
initiatives, policies and locally implemented projects in the field of
energy efficiency are described.
Abstract: Member States shall establish zones and
agglomerations throughout their territory to assess and manage air
quality in order to comply with European directives.
In Italy decree 155/2010, transposing Directive 2008/50/EC on
ambient air quality and cleaner air for Europe, merged into a single
act the previous provisions on ambient air quality assessment and
management, including those resulting from the implementation of
Directive 2004/107/EC relating to arsenic, cadmium, nickel, mercury
and polycyclic aromatic hydrocarbons in ambient air.
Decree 155/2010 introduced stricter rules for identifying zones on
the basis of the characteristics of the territory in spite of considering
pollution levels, as it was in the past. The implementation of such
new criteria has reduced the great variability of the previous zoning,
leading to a significant reduction of the total number of zones and to
a complete and uniform ambient air quality assessment and
management throughout the Country.
The present document is related to the new zones definition in
Italy according to Decree 155/2010. In particular the paper contains
the description and the analysis of the outcome of zoning and
classification.
Abstract: The number of Ground Motion Prediction Equations
(GMPEs) used for predicting peak ground acceleration (PGA) and
the number of earthquake recordings that have been used for fitting
these equations has increased in the past decades. The current PF-L
database contains 3550 recordings. Since the GMPEs frequently
model the peak ground acceleration the goal of the present study was
to refit a selection of 44 of the existing equation models for PGA in
light of the latest data. The algorithm Levenberg-Marquardt was used
for fitting the coefficients of the equations and the results are
evaluated both quantitatively by presenting the root mean squared
error (RMSE) and qualitatively by drawing graphs of the five best
fitted equations. The RMSE was found to be as low as 0.08 for the
best equation models. The newly estimated coefficients vary from the
values published in the original works.
Abstract: Water flow management is one of the most important
parts of river engineering. Non-uniformity distribution of rainfall and
various flow demand with unreasonable flow management will be
caused destroyed of river ecosystem. Then, it is very serious to
determine ecosystem flow requirement. In this paper, Flow duration
curve indices method which has hydrological based was used to
evaluate environmental flow in Gharasou River, Ardabil, Iran. Using
flow duration curve, Q90 and Q95 for different return periods were
calculated. Their magnitude were determined as 1-day, 3-day, 7-day
and 30 day. According the second method, hydraulic alteration
indices often had low and medium range. In order to maintain river at
an acceptable ecological condition, minimum daily discharge of
index Q95 is 0.7 m3.s-1.
Abstract: At certain depths during large diameter displacement
pile driving, rebound well over 0.25 inches was experienced,
followed by a small permanent-set during each hammer blow. High
pile rebound (HPR) soils may stop the pile driving and results in a
limited pile capacity. In some cases, rebound leads to pile damage,
delaying the construction project, and the requiring foundations
redesign. HPR was evaluated at seven Florida sites, during driving of
square precast, prestressed concrete piles driven into saturated, fine
silty to clayey sands and sandy clays. Pile Driving Analyzer (PDA)
deflection versus time data recorded during installation, was used to
develop correlations between cone penetrometer (CPT) pore-water
pressures, pile displacements and rebound. At five sites where piles
experienced excessive HPR with minimal set, the pore pressure
yielded very high positive values of greater than 20 tsf. However, at
the site where the pile rebounded, followed by an acceptable
permanent-set, the measured pore pressure ranged between 5 and 20
tsf. The pore pressure exhibited values of less than 5 tsf at the site
where no rebound was noticed. In summary, direct correlations
between CPTu pore pressure and rebound were produced, allowing
identification of soils that produce HPR.