Abstract: Absorption spectra of infra-red (IR) radiation of the
disperse water medium absorbing the most important greenhouse
gases: CO2 , N2O , CH4 , C2H2 , C2H6 have been calculated by
the molecular dynamics method. Loss of the absorbing ability at the
formation of clusters due to a reduction of the number of centers
interacting with IR radiation, results in an anti-greenhouse effect.
Absorption of O3 molecules by the (H2O)50 cluster is investigated
at its interaction with Cl- ions. The splitting of ozone molecule on
atoms near to cluster surface was observed. Interaction of water
cluster with Cl- ions causes the increase of integrated intensity of
emission spectra of IR radiation, and also essential reduction of the
similar characteristic of Raman spectrum. Relative integrated
intensity of absorption of IR radiation for small water clusters was
designed. Dependences of the quantity of weight on altitude for
vapor of monomers, clusters, droplets, crystals and mass of all
moisture were determined. The anti-greenhouse effect of clusters was
defined as the difference of increases of average global temperature
of the Earth, caused by absorption of IR radiation by free water
molecules forming clusters, and absorption of clusters themselves.
The greenhouse effect caused by clusters makes 0.53 K, and the antigreenhouse
one is equal to 1.14 K. The increase of concentration of
CO2 in the atmosphere does not always correlate with the
amplification of greenhouse effect.
Abstract: Paleoclimate was reconstructed by the clay mineral
assemblages of shale units of Pabdeh (Paleocene- Oligocene), Gurpi
(Upper Cretaceous), Kazhdumi (Albian-Cenomanian) and Gadvan
(Aptian-Neocomian) formations in the Bangestan anticline. To
compare with clay minerals assemblages in these formations,
selected samples also taken from available formations in drilled wells
in Ahvaz, Marun, Karanj, and Parsi oil fields. Collected samples
prepared using standard clay mineral methodology. They were
treated as normal, glycolated and heated oriented glass slides. Their
identification was made on X-Ray diffractographs. Illite % varies
from 8 to 36. Illite quantity increased from Pabdeh to Gurpi
Formation. This may be due to dominant dry climate. Kaolinite is in
range of 12-49%. Its variation style in different formations could be a
marker of climate changes from wet to dry which is supported by the
lithological changes. Chlorite (4-28%) can also be detected in those
samples without any kaolinite. Mixed layer minerals as the mixture
of illite-chlorite and illite-vermiculite-montmorillonite are varied
from 6 to 36%, decreased during Kazhdumi deposition from the base
to the top. This result may be according to decreasing of illite
leaching process. Vermiculite was also determined in very less
quantity and found in those units without kaolinite. Montmorillonite
varies from 8 to 43%, and its presence is due to terrestrial
depositional condition. Stratigraphical documents is also supported
this idea that clay mineral distribution is a function of the climate
changes. It seems, thus, the present results can be indicated a possible
procedure for ancient climate changes evaluation.
Abstract: Due to the growth of the urban area towards lands
contaminated with ancient tails, in this work we evaluated if the
leaching with calcium thiosulfate (CaS2O3) for the recovery of silver,
gold and mercury from this soil, also dissolves arsenic, cadmium and
lead; for this, we determined their quantity per each fraction of size
of particle of the soil before and after the dissolution. Half of the soil
samples were leached in the plant Beneficiadora de Jales del Centro,
S. A. de C.V. and the rest of them remained in the laboratory. The
ICP-OES technique was used to determine the amounts of arsenic,
cadmium and lead, in the samples of both lots. The soil samples were
collected in a neighboring area at El Lampotal, Vetagrande,
Zacatecas, México, with an extension of 600 m2 at 22º52' 37.69'' N,
102º25' 11.73'' W. The amount of arsenic, cadmium and lead found
in nonleached soil and for a particle size of 47 μm was 203.72±3.73,
33.63±1.31 and 3480.99±20.4 mg/kg respectively.
Abstract: Recent research on seeds of bio-diesel plants like
Jatropha curcas, constituting 40-50% bio-crude oil indicates its
potential as one of the most promising alternatives to conventional
sources of energy. Also, limited studies on utilization of de-oiled cake
have revealed that Jatropha bio-waste has good potential to be used as
organic fertilizers produced via aerobic and anaerobic treatment.
However, their commercial exploitation has not yet been possible. The
present study aims at developing appropriate bio-processes and
formulations utilizing Jatropha seed cake as organic fertilizer, for
improving the growth of Polianthes tuberose L. (Tuberose). Pot
experiments were carried out by growing tuberose plants on soil
treated with composted formulations of Jatropha de-oiled cake, Farm
Yard Manure (FYM) and inorganic fertilizers were also blended in
soil. The treatment was carried out through soil amendment as well as
foliar spray. The growth and morphological parameters were
monitored for entire crop cycle.
The growth Length and number of leaves, spike length, rachis
length, number of bulb per plant and earliness of sprouting of bulb and
yield enhancement were comparable to that achieved under inorganic
fertilizer. Furthermore, performance of inorganic fertilizer also showed
an improvement when blended with composted bio-waste. These
findings would open new avenues for Jatropha based bio-wastes to be
composted and used as organic fertilizers for commercial floriculture.
Abstract: The present investigation was undertaken to explore the biogas potentiality of Jatropha (Jatropha curcas, Euphorbiaceae) Fruit Coat (JFC) alone and in combination with cattle dung (CD) in various proportions at 15 per cent total solids by batch phase anaerobic digestion for a period of ten weeks HRT (Hydraulic Retention Time) under a temperature of 35°C+1°C. The maximum biogas production was noticed in Cattle dung and Jatropha Fruit Coat in 2:1 ratio with 403.84 L/kg dry matter followed by 3:1,1:2, 1:1 and 1:3 having 329.66, 219.77, 217.79, 203.64 L /kg dm respectively as compared to 178.49 L/kg dm in CD alone. The JFC alone found to produce 91 per cent of total biogas that obtained from Cattle dung. The per cent methane content of the biogas in all the treatments was found on par with Cattle dung.
Abstract: The objectives of this study are to determine the
effects of soil cover type on characteristics of leachates generated
from landfill lysimeters. Four lysimeters with diameter and height
of 0.15 and 3.00 m, respectively, were prepared. Three lysimeters
were filled with municipal waste and three different cover soil types
i.e. sandy loam soil, silty loam soil and clay soil while another
lysimeter was filled solely with municipal waste. The study was
conducted in the rainy season. Leachate quantities were measured
every day and leachate characteristics were determined once a week.
The cumulative leachate quantity from the lysimeter filled solely
with municipal waste was found to be around 27% higher than the
lysimeters using cover soils. There were no any differences of the
cumulative leachate amounts generated from the lysimeters using
three types of soils. The comparison of the total mass of pollutants
generated from all lysimeters showed that the lysimeter filled solely
with municipal waste generated the maximum quantities of
pollutants. Among the lysimeters using different types of soils, the
lysimeter using sandy loam soil generated the lowest amount of most
of pollutants, compared with the lysimeters using silty loam and clay
soils. It can be concluded that in term of pollutant attenuation in the
leachate, a sandy loam is the most suitable soil to be used as a cover
soil in the landfill.
Abstract: The Long-range Energy and Alternatives Planning (LEAP) energy planning system has been developed for South Africa, for the 2005 base year and a limited number of plausible future scenarios that may have significant implications (negative or positive) in terms of environmental impacts. The system quantifies the national energy demand for the domestic, commercial, transport, industry and agriculture sectors, the supply of electricity and liquid fuels, and the resulting emissions. The South African National Energy Research Institute (SANERI) identified the need to develop an environmental assessment tool, based on the LEAP energy planning system, to provide decision-makers and stakeholders with the necessary understanding of the environmental impacts associated with different energy scenarios. A comprehensive analysis of indicators that are used internationally and in South Africa was done and the available data was accessed to select a reasonable number of indicators that could be utilized in energy planning. A consultative process was followed to determine the needs of different stakeholders on the required indicators and also the most suitable form of reporting. This paper demonstrates the application of Energy Environmental Sustainability Indicators (EESIs) as part of the developed tool, which assists with the identification of the environmental consequences of energy generation and use scenarios and thereby promotes sustainability, since environmental considerations can then be integrated into the preparation and adoption of policies, plans, programs and projects. Recommendations are made to refine the tool further for South Africa.
Abstract: Several studies have shown the association between
ambient particulate matter (PM) and adverse health effects and
climate change, thus highlighting the need to limit the anthropogenic
sources of PM. PM Exposure is commonly monitored as mass
concentration of PM10 (particle aerodynamic diameter < 10μm) or
PM2.5 (particle aerodynamic diameter < 2.5μm), although increasing
toxicity with decreasing aerodynamic diameter has been reported due
to increased surface area and enhanced chemical reactivity with other
species. Additionally, the light scattering properties of PM increases
with decreasing size. Hence, it is important to study the chemical
characterization of finer fraction of the particulate matter and to
identify their sources so that they can be controlled appropriately to a
large extent at the sources before reaching to the receptors.
Abstract: The aim of this work is to study the possible use of
stone cutting sludge waste in concrete production, which would
reduce both the environmental impact and the production cost .Slurry
sludge was used a source of water in concrete production, which was
obtained from Samara factory/Jordan, The physico-chemical and
mineralogical characterization of the sludge was carried out to
identify the major components and to compare it with the typical
sand used to produce concrete. Samples analysis showed that 96% of
slurry sludge volume is water, so it should be considered as an
important source of water. Results indicated that the use of slurry
sludge as water source in concrete production has insignificant effect
on compression strength, while it has a sharp effect on the slump
values. Using slurry sludge with a percentage of 25% of the total
water content obtained successful concrete samples regarding slump
and compression tests. To clarify slurry sludge, settling process can
be used to remove the suspended solid. A settling period of 30 min.
obtained 99% removal efficiency. The clarified water is suitable for
using in concrete mixes, which reduce water consumption, conserve
water recourses, increase the profit, reduce operation cost and save
the environment. Additionally, the dry sludge could be used in the
mix design instead of the fine materials with sizes < 160 um. This
application could conserve the natural materials and solve the
environmental and economical problem caused by sludge
accumulation.
Abstract: The effects of upflow liquid velocity (ULV) on
performance of expanded granular sludge bed (EGSB) system were
investigated. The EGSB reactor, made from galvanized steel pipe
0.10 m diameter and 5 m height, had been used to treat piggery
wastewater, after passing through acidification tank. It consisted of
39.3 l working volume in reaction zone and 122 l working volume in
sedimentation zone, at the upper part. The reactor was seeded with
anaerobically digested sludge and operated at the ULVs of 4, 8, 12
and 16 m/h, consecutively, corresponding to organic loading rates of
9.6 – 13.0 kg COD/ (m3.d). The average COD concentrations in the
influent were 9,601 – 13,050 mg/l. The COD removal was not
significantly different, i.e. 93.0% - 94.0%, except at ULV 12 m/h where
SS in the influent was exceptionally high so that VSS washout had
occurred, leading to low COD removal. The FCOD and VFA
concentrations in the effluent of all experiments were not much
different, indicating the same range of treatment performance. The
biogas production decreased at higher ULV and ULV of 4 m/h is
suggested as design criterion for EGSB system.
Abstract: Coarse and fine particulate matter were collected at a
residential area at Vashi, Navi Mumbai and the filter samples were
analysed for trace elements using PIXE technique. The trend of
particulate matter showed higher concentrations during winter than
the summer and monsoon concentration levels. High concentrations
of elements related to soil and sea salt were found in PM10 and
PM2.5. Also high levels of zinc and sulphur found in the particulates
of both the size fractions. EF analysis showed enrichment of Cu, Cr
and Mn only in the fine fraction suggesting their origin from
anthropogenic sources. The EF value was observed to be maximum
for As, Pb and Zn in the fine particulates. However, crustal derived
elements showed very low EF values indicating their origin from
soil. The PCA based multivariate studies identified soil, sea salt,
combustion and Se sources as common sources for coarse and
additionally an industrial source has also been identified for fine
particles.
Abstract: Cameron Highlands is a mountainous area subjected
to torrential tropical showers. It extracts 5.8 million liters of water
per day for drinking supply from its rivers at several intake points.
The water quality of rivers in Cameron Highlands, however, has
deteriorated significantly due to land clearing for agriculture,
excessive usage of pesticides and fertilizers as well as construction
activities in rapidly developing urban areas. On the other hand, these
pollution sources known as non-point pollution sources are diverse
and hard to identify and therefore they are difficult to estimate.
Hence, Geographical Information Systems (GIS) was used to provide
an extensive approach to evaluate landuse and other mapping
characteristics to explain the spatial distribution of non-point sources
of contamination in Cameron Highlands. The method to assess
pollution sources has been developed by using Cameron Highlands
Master Plan (2006-2010) for integrating GIS, databases, as well as
pollution loads in the area of study. The results show highest annual
runoff is created by forest, 3.56 × 108 m3/yr followed by urban
development, 1.46 × 108 m3/yr. Furthermore, urban development
causes highest BOD load (1.31 × 106 kgBOD/yr) while agricultural
activities and forest contribute the highest annual loads for
phosphorus (6.91 × 104 kgP/yr) and nitrogen (2.50 × 105 kgN/yr),
respectively. Therefore, best management practices (BMPs) are
suggested to be applied to reduce pollution level in the area.