Abstract: Recently, RESS (Rapid Expansion Supercritical Solution) method has been used by researchers to produce fine particles for pharmaceutical drug substances. Since RESS technology acknowledges a lot of benefits compare to conventional method of ginger extraction, it is suggested to use this method to explore particle formation of bioactive compound from powder ginger. The objective of this research is to produce direct solid oil particles formation from ginger rhizome which contains valuable compounds by using RESS-CO2 process. RESS experiments were carried using extraction pressure of 3000, 4000, 5000, 6000 and 7000psi and at different extraction temperature of 40, 45, 50, 55, 60, 65 and 70°C for 40 minutes extraction time and contant flowrate (24ml/min). From the studies conducted, it was found that at extraction pressure 5000psi and temperature 40°C, the smallest particle size obtained was 2.22μm on 99 % reduction from the original size of 370μm.
Abstract: Lipase is one of biocatalyst which is applied commercially for the process in industries, such as bioenergy, food, and pharmaceutical industry. Nowadays, biocatalysts are preferred in industries because they work in mild condition, high specificity, and reduce energy consumption (high pressure and temperature). But, the usage of lipase for industry scale is limited by economic reason due to the high price of lipase and difficulty of the separation system. Immobilization of lipase is one of the solutions to maintain the activity of lipase and reduce separation system in the process. Therefore, we conduct a study about lipase immobilization with the adsorption-cross linking method using glutaraldehyde because this method produces high enzyme loading and stability. Lipase is immobilized on different kind of resin with the various functional group. Highest enzyme loading (76.69%) was achieved by lipase immobilized on anion macroporous which have anion functional group (OH‑). However, highest activity (24,69 U/g support) through olive oil emulsion method was achieved by lipase immobilized on anion macroporous-chitosan which have amino (NH2) and anion (OH-) functional group. In addition, it also success to produce biodiesel until reach yield 50,6% through interesterification reaction and after 4 cycles stable 63.9% relative with initial yield. While for Aspergillus, niger lipase immobilized on anion macroporous-kitosan have unit activity 22,84 U/g resin and yield biodiesel higher than commercial lipase (69,1%) and after 4 cycles stable reach 70.6% relative from initial yield. This shows that optimum functional group on support for immobilization with adsorption-cross linking is the support that contains amino (NH2) and anion (OH-) functional group because they can react with glutaraldehyde and binding with enzyme prevent desorption of lipase from support through binding lipase with a functional group on support.
Abstract: In the present study, an ecofriendly biocomposite namely calcium alginate immobilized Ammi Visnaga (Khella) extraction waste (SWAV/CA) was prepared by electrostatic extrusion method and used on the cadmium biosorption from aqueous phase with and without the assistance of ultrasound in batch conditions. The influence of low frequency ultrasound (37 and 80 KHz) on the cadmium biosorption kinetics was studied. The obtained results show that the ultrasonic irradiation significantly enhances and improves the efficiency of the cadmium removal. The Pseudo first order, Pseudo-second-order, Intraparticle diffusion, and Elovich models were evaluated using the non-linear curve fitting analysis method. Modeling of kinetic results shows that biosorption process is best described by the pseudo-second order and Elovich, in both the absence and presence of ultrasound.
Abstract: Effect of enzyme on the yield and chemical composition of Artemisia campestris essential oil is reported in the present study. It was demonstrated that enzyme facilitated the extraction of essential oil with increase in oil yield and did not affect any noticeable change in flavour profile of the volatile oil. Essential oil was tested for antibacterial activity using Escherichia coli; which was extremely sensitive against control with the largest inhibition (29mm), whereas Staphylococcus aureus was the most sensitive against essential oil obtained from enzymatic pre-treatment with the largest inhibition zone (25mm). The antioxidant activity of the essential oil with hemicellulase pre-treatment (EO2) and control sample (EO1) was determined through reducing power. It was significantly lower than the standard drug (vitamin C) in this order: vitamin C˃EO2˃EO1.
Abstract: Flue gas desulfurization gypsum (FGD) is a waste
material arouse from coal power plants. Hydroxyapatite (HAP) is a
biomaterial with porous structure. In this study, FGD gypsum which
retrieved from coal power plant in Turkey was characterized and
HAP particles which can be used as an adsorbent in wastewater
treatment application were synthesized from the FGD gypsum. The
raw materials are characterized by using X Ray Diffraction (XRD)
and Fourier transform infrared spectroscopy (FT-IR) techniques and
produced HAP are characterized by using XRD. As a result, HAP
particles were synthesized at the molar ratio of 5:10, 5:15, 5:20, 5:24,
at room temperature, in alkaline medium (pH=11) and in 1 hour-reaction
time. Among these conditions, 5:20 had the best result.
Abstract: Torrefaction of biomass pellets is considered as a
useful pretreatment technology in order to convert them into a high
quality solid biofuel that is more suitable for pyrolysis, gasification,
combustion, and co-firing applications. In the course of torrefaction,
the temperature varies across the pellet, and therefore chemical
reactions proceed unevenly within the pellet. However, the
uniformity of the thermal distribution along the pellet is generally
assumed. The torrefaction process of a single cylindrical pellet is
modeled here, accounting for heat transfer coupled with chemical
kinetics. The drying sub-model was also introduced. The nonstationary
process of wood pellet decomposition is described by the
system of non-linear partial differential equations over the
temperature and mass. The model captures well the main features of
the experimental data.
Abstract: In this current contribution, authors are dedicated to
investigate influence of the crystal lamellae orientation on
electromechanical behaviors of relaxor ferroelectric Poly
(vinylidene fluoride –trifluoroethylene -chlorotrifluoroethylene)
(P(VDF-TrFE-CTFE)) films by control of polymer microstructure,
aiming to picture the full map of structure-property relationship. In
order to define their crystal orientation films, terpolymer films were
fabricated by solution-casting, stretching and hot-pressing process.
Differential scanning calorimetry, impedance analyzer, and tensile
strength techniques were employed to characterize crystallographic
parameters, dielectric permittivity, and elastic Young’s modulus
respectively. In addition, large electrical induced out-of-plane
electrostrictive strain was obtained by cantilever beam mode.
Consequently, as-casted pristine films exhibited surprisingly high
electrostrictive strain 0.1774% due to considerably small value of
elastic Young’s modulus although relatively low dielectric
permittivity. Such reasons contributed to large mechanical elastic
energy density. Instead, due to 2 folds increase of elastic Young’s
modulus and less than 50% augmentation of dielectric constant, fullycrystallized
film showed weak electrostrictive behavior and
mechanical energy density as well. And subjected to mechanical
stretching process, Film C exhibited stronger dielectric constant and
out-performed electrostrictive strain over Film B because edge-on
crystal lamellae orientation induced by uniaxially mechanical stretch.
Hot-press films were compared in term of cooling rate. Rather large
electrostrictive strain of 0.2788% for hot-pressed Film D in
quenching process was observed although its dielectric permittivity
equivalent to that of pristine as-casted Film A, showing highest
mechanical elastic energy density value of 359.5 J/m3. In hot-press
cooling process, dielectric permittivity of Film E saw values at 48.8
concomitant with ca.100% increase of Young’s modulus. Films with
intermediate mechanical energy density were obtained.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: This work aims to investigate the structure–property
relationship in ternary nanocomposites consisting of polypropylene
as the matrix, polyamide 66 as the minor phase and treated nanoclay
DELLITE 67G as the reinforcement. All PP/PA66/Nanoclay systems
with polypropylene grafted maleic anhydride PP-g-MAH as a
compatibilizer were prepared via melt compounding and
characterized in terms of nanoclay content. Morphological structure
was investigated by scanning electron microscopy. The rheological
behavior of the nanocomposites was determined by various methods,
viz melt flow index (MFI) and parallel plate rheological
measurements. The PP/PP-g-MAH/PA66 nanocomposites showed a homogeneous
morphology supporting the compatibility improvement between PP,
PA66, and nanoclay. SEM results revealed the formation of
nanocomposites as the nanoclay was intercalated and exfoliated. In
the ternary nanocomposites, the rheological behavior showed that, the
complex viscosity is increased with increasing the nanoclay. The results showed that the use of nanoclay affects the variations
of storage modulus (G′), loss modulus (G″) and the melt elasticity.
Abstract: This paper presents the effects of mixing procedures
on mechanical properties of flyash-based geopolymer matrices
containing nanosilica (NS) at 0.5%, 1.0%, 2.0%, and 3.0% by weight.
Comparison is made with conventional mechanical dry-mixing of NS
with flyash and wet-mixing of NS in alkaline solutions. Physical and
mechanical properties are investigated using X-Ray Diffraction
(XRD) and Scanning Electron Microscope (SEM). Results show that
generally the addition of NS particles enhanced the microstructure
and improved flexural and compressive strengths of geopolymer
nanocomposites. However, samples, prepared using dry-mixing
approach, demonstrate better physical and mechanical properties
comparing to wet-mixing samples.
Abstract: Low density polyethylene (LDPE) nanocomposites
with 3, 5 and 7 wt. % cobalt ferrite (CoFe2O4) nanopowder fabricated
with extrusion mixing and followed up by hot press to reach compact
samples. The transmission/reflection measurements were carried out
with a network analyzer in the frequency range of 8-12 GHz. By
increasing the percent of CoFe2O4 nanopowder, reflection loss (S11)
increases, while transferring loss (S21) decreases. Reflectivity (R)
calculations made using S11 and S21. Increase in percent of CoFe2O4
nanopowder up to 7 wt. % in composite leaded to higher reflectivity
amount, and revealed that increasing the percent of CoFe2O4
nanopowder up to 7 wt. % leads to further microwave absorption in
8-12 GHz range.
Abstract: Despite the wide spread use of synthetic dyes, natural
dyes are still exploited and used to enhance its inherent aesthetic
qualities as a major material for beautification of the body. Centuries
before the discovery of synthetic dyes, natural dyes were the only
source of dye open to mankind. Dyes are extracted from plant -
leaves, roots and barks, insect secretions, and minerals. However,
research findings have made it clear that of all, plants- leaves, roots,
barks or flowers are the most explored and exploited in which henna
(Lawsonia innermis L.) is one of those plants. Experiment has also
shown that henna is used in body painting in conjunction with an
alkaline (Ammonium Sulphate) as a fixing agent. This of course
gives a clue that if colour derived from henna is properly
investigated, it may not only be used for body decoration but
possibly, may have affinity to fiber substrate. This paper investigates
the dyeing potentials – dye ability and fastness qualities of henna dye
extracts on cotton and linen fibers using mordants like ammonium
sulphate and other alkalis (hydrosulphate and caustic soda, potash,
common salt, potassium alum). Hot and cold water and ethanol
solvent were used in the extraction of the dye to investigate the most
effective method, dye ability, and fastness qualities of these extracts
under room temperature. The results of the experiment show that
cotton have a high rate of dye intake than other fiber. On a similar
note, the colours obtained depend most on the solvent used. In
conclusion, hot water extraction appears more effective. While the
colours obtained from ethanol and both cold hot methods of
extraction range from light to dark yellow, light green to army green
and to some extent shades of brown hues.
Abstract: Lightweight and efficient structures have the aim to
enhance the efficiency of the components in various industries.
Toward this end, composites are one of the most widely used
materials because of durability, high strength and modulus, and low
weight. One type of the advanced composites is grid-stiffened
composite (GSC) structures, which have been extensively considered
in aerospace, automotive, and aircraft industries. They are one of the
top candidates for replacing some of the traditional components,
which are used here. Although there are a good number of published
surveys on the design aspects and fabrication of GSC structures, little
systematic work has been reported on their material modification to
improve their properties, to our knowledge. Matrix modification
using nanoparticles is an effective method to enhance the flexural
properties of the fibrous composites. In the present study, a silanecoupling
agent (3-glycidoxypropyltrimethoxysilane/3-GPTS) was
introduced onto the silica (SiO2) nanoparticle surface and its effects
on the three-point flexural response of isogrid E-glass/epoxy
composites were assessed. Based on the Fourier Transform Infrared
Spectrometer (FTIR) spectra, it was inferred that the 3-GPTS
coupling agent was successfully grafted onto the surface of SiO2
nanoparticles after modification. Flexural test revealed an
improvement of 16%, 14%, and 36% in stiffness, maximum load and
energy absorption of the isogrid specimen filled with 3 wt.% 3-
GPTS/SiO2 compared to the neat one. It would be worth mentioning
that in these structures, considerable energy absorption was observed
after the primary failure related to the load peak. In addition, 3-
GPTMS functionalization had a positive effect on the flexural
behavior of the multiscale isogrid composites. In conclusion, this
study suggests that the addition of modified silica nanoparticles is a
promising method to improve the flexural properties of the gridstiffened
fibrous composite structures.
Abstract: Hard coatings are widely used in cutting and forming
tool industries. Titanium Nitride (TiN) possesses good hardness,
strength, and corrosion resistance. The coating properties are
influenced by many process parameters. The coatings were deposited
on steel substrate by changing the process parameters such as
substrate temperature, nitrogen flow rate and target power in a D.C
planer magnetron sputtering. The structure of coatings were analysed
using XRD. The hardness of coatings was found using Micro
hardness tester. From the experimental data, a regression model was
developed and the optimum response was determined using Response
Surface Methodology (RSM).
Abstract: Zinc borates are used as a multi-functional flame
retardant additive for its high dehydration temperature. In this study,
the method of ultrasonic mixing was used in the synthesis of zinc
borates. The reactants of zinc oxide (ZnO) and boric acid (H3BO3)
were used at the constant reaction parameters of 90°C reaction
temperature and 55 min of reaction time. Several molar ratios of
ZnO:H3BO3 (1:1, 1:2, 1:3, 1:4 and 1:5) were conducted for the
determination of the optimum reaction ratio. Prior to synthesis the
characterization of the synthesized zinc borates were made by X-Ray
Diffraction (XRD) and Fourier Transform Infrared Spectroscopy
(FT-IR). From the results Zinc Oxide Borate Hydrate
[Zn3B6O12.3.5H2O], were synthesized optimum at the molar ratio of
1:3, with a reaction efficiency of 95.2%.
Abstract: In the present work, forming limit diagrams and strain
distribution profile diagrams for extra deep drawing steel at room and
elevated temperatures have been determined experimentally by
conducting stretch forming experiments by using designed and
fabricated warm stretchforming tooling setup. With the help of
forming Limit Diagrams (FLDs) and strain, distribution profile
diagrams the formability of Extra Deep Drawing steel has been
analyzed and co-related with mechanical properties like strain
hardening COEFFICIENT (n) and normal anisotropy (r−). Mechanical
properties of EDD steel from room temperature to 4500C were
determined and discussed the impact of temperature on the properties
like work hardening exponent (n) anisotropy (r-) and strength
coefficient of the material. In addition, the fractured surfaces after
stretching have undergone the some metallurgical investigations and
attempt has been made to co-relate with the formability of EDD steel
sheets. They are co-related and good agreement with FLDs at various
temperatures.
Abstract: This paper describes the development of new class of
epoxy based rice husk filled jute reinforced composites. Rice husk
flour is added in 0%, 1%, 3%, 5% by weight. Epoxy resin and
triethylenetetramine (T.E.T.A) is used as matrix and hardener
respectively. It investigates the mechanical properties of the
composites and a comparison is done for monolithic jute composite
and the filled ones. The specimens are prepared according to the
ASTM standards and experimentation is carried out using INSTRON
8801. The result shows that with the increase of filler percentage the
tensile properties increases but compressive and flexural properties
decreases.
Abstract: The strain intensity and redundant strains, dependent
in multistage TRIP wire drawing processes from values used single
partial reductions, should influence on the intensity of transformation
the retained austenite into martensite and thereby on mechanical
properties of drawn wires. The numerical analysis of drawing
processes with use of Drawing 2D programme, for steel wires made
from TRIP steel with 0,29% has been shown in the work. The change
of strain intensity εc and the values of redundant strain εxy, has been
determined for particular draws in dependence of used single partial
reductions.
Abstract: This paper focuses on the mathematical modeling for
solidification of Al alloy in a cube mold cavity to study the
solidification behavior of casting process. The parametric
investigation of solidification process inside the cavity was
performed by using computational solidification/melting model
coupled with Volume of fluid (VOF) model. The implicit filling
algorithm is used in this study to understand the overall process from
the filling stage to solidification in a model metal casting process.
The model is validated with past studied at same conditions. The
solidification process is analyzed by including the effect of pouring
velocity as well as natural convection from the wall and geometry of
the cavity. These studies show the possibility of various defects
during solidification process.
Abstract: In the present study, feasibility of the selective surface
hydrophilization of polyvinyl chloride (PVC) by microwave treatment
was evaluated to facilitate the separation from automotive shredder
residue (ASR), by the froth flotation. The combination of 60 sec
microwave treatment with PAC, a sharp and significant decrease about
16.5° contact angle of PVC was observed in ASR plastic compared
with other plastics. The microwave treatment with the addition of PAC
resulted in a synergetic effect for the froth flotation, which may be a
result of the 90% selective separation of PVC from ASR plastics, with
82% purity. While, simple mixing with a nanometallic Ca/CaO/PO4
dispersion mixture immobilized 95-100% of heavy metals in ASR
soil/residues. The quantity of heavy metals leached from thermal
residues after treatment by nanometallic Ca/CaO/PO4 was lower than
the Korean standard regulatory limit for hazardous waste landfills.
Microwave treatment can be a simple and effective method for PVC
separation from ASR plastics.