Study on the Electrochemical Performance of Graphene Effect on Cadmium Oxide in Lithium Battery
Graphene and CdO with different stoichiometric ratios of Cd(CH₃COO)₂ and graphene samples were prepared by hydrothermal reaction. The crystalline phases of pure CdO and 3CdO:1graphene were identified by X-ray diffraction (XRD). The particle morphology was studied with SEM. Furthermore, impedance measurements were applied. Galvanostatic measurements for the cells were carried out using potential limits between 0.01 and 3 V vs. Li/Li⁺. The current cycling intensity was 10⁻⁴ A. The specific discharge capacity of 3CdO-1G cell was about 450 Ah.Kg⁻¹ up to more than 100 cycles.
[1] M. Armand and J. M. Tarascon, "Building Better Batteries," Nature, vol. 451, pp. 652-657, Feb. 2008.
[2] K. Nechev, "SAFT's Very High Power Li-Ion Technology," in 3rd Annual International Conference Lithium Mobile Power, San Diego, CA, 2007.
[3] A. Y. Shenouda, "Structure and electrochemical behavior of lithium vanadate materials for lithium batteries," Electrochimica Acta, vol. 51, pp. 5973-5981, May 2006.
[4] A. Y. Shenouda and K.R. Murali, "Electrochemical properties of doped lithium titanate compounds and their performance in lithium rechargeable batteries". J. Power Sources, vol. 176, pp. 332-339, 2008.
[5] A. Y. Shenouda and H. K. Liu, “Electrochemical behaviour of tin borophosphate negative electrodes for energy storage systems,” J. Power Sources, vol. 185, pp. 1386-1391, August 2008.
[6] A. Y. Shenouda, H. K. Liu, "Studies on electrochemical behaviour of zinc-doped LiFePO4 for lithium battery positive electrode," J. Alloys and Compd., vol. 477, pp. 498-503, Dec. 2009.
[7] A. Y. Shenouda, Hua K. Liu, "Preparation, Characterization, and Electrochemical Performance of Li2CuSnO4 and Li2CuSnSiO6 Electrodes for Lithium Batteries," J. Electrochem. Soc., vol. 157, pp. A 1183-A 1187, Nov. 2010.
[8] A.Y. Shenouda E. M. El Sayed and H. K. Liu, "Preparation, Characterization and Electrochemical Performance of LiNixCoyCuzMn2-x-y-zO4 as Positive Electrodes in Lithium Rechargeable Batteries," J. New Materials for Electrochemical Systems", vol. 14, pp. 19-26, Feb. 2011.
[9] S. H. Wu, K.M. Hsiao, W.R. Liu, "The preparation and characterization of olivine LiFePO4 by a solution method," J. Power Sources, vol. 146, pp. 550-554, August 2005.
[10] Q. R. Hu, S. L. Wang, Y. Zhang, W.H. Tang, "Synthesis of cobalt sulfide nanostructures by a facile solvothermal growth process," J. Alloys and Compd., vol. 491, pp. 707–711, Feb. 2010.
[11] S.T. Mane, S. S. Kamble, L.P. Deshmukh, "Cobalt sulphide thin films: Chemical bath deposition, growth and properties," Mater. Letters, vol. 65 pp. 2639–2641, Sept. 2011.
[12] M. Lei, X. L. Fu, Y. B. Zhang, H. J. Yang, Y. T. Huang, L. Zhang, Y. G. Wang, "Synthesis of CoS nanoplates and their ferromagnetic properties," Mater. Letters, vol. 71, pp. 11-14, March 2012.
[13] M. R. Yang, W. H. Ke, S. H. Wu, "Preparation of LiFePO4 powders by co-precipitation," J. Power Sources, vol. 146, pp. 539-543, August 2005.
[14] A. Y. Shenouda and A. A. Momchilov, "A study on graphene/tin oxide performance as negative electrode compound for lithium battery application," J. Materials Science: Materials in Electronics, vol. 30, pp.79–90, Jan. 2019.
[15] J. Feng, S. Xiong, Y. Qian, L. Yin, "Synthesis of nanosized cadmium oxide (CdO) as a novel high capacity anode material for Lithium-ion batteries: influence of carbon nanotubes," Electrochimica Acta, vol. 129, pp. 107–112, Feb. 2014.
[16] F. Zhang, R. Zhang, J. Feng, Y. Qian, CdCO3/Carbon nanotube nanocomposites as anode materials for advanced lithium-ion batteries," Mater. Letters, vol. 114, pp. 115–118, Jan. 2014.
[17] S. Grugeon, S. Laruelle, R. Herrera-Urbina, L. Dupont, P. Poizot, J. M. Tarascon, Particle Size Effects on the Electrochemical Performance of Copper Oxides toward Lithium," J. Electrochem. Soc., vol. 148, pp. A285–A292, April 2001.
[18] P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J. M. Tarascon, "Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries," Nature, vol. 407, pp. 496–499, Sept. 2000.
[19] J. Feng, C. Wang, Y. Qian, "In situ synthesis of cadmium germanates (Cd2Ge2O6)/reduced graphene oxide nanocomposites as novel high capacity anode materials for advanced lithium-ion batteries," Mater. Letters, vol. 122, pp. 327-330, May 2014.
[20] A. L. M. Reddy, M. M. Shaijumon, S.R. Gowda, P.M. Ajayan, "coaxial Mno2/carbon nanotube array electrodes for high-performance lithium batteries," Nano Lett., vol. 9, pp. 1002–1006, March 2009.
[21] Y. Wang, H.C. Zheng, J.Y. Lee, "Highly Reversible Lithium Storage in Porous SnO2 Nanotubes with Coaxially Grown Carbon Nanotube Overlayers," Adv. Mater. vol. 18, pp. 645–649, March 2006.
[22] Q. Wei, G. C. Liu, C. Zhang, X. J. Hong, Y. P. Cai, "Novel honeycomb silicon wrapped in reduced graphene oxide/CNT system as high-stability anodes for lithium-ion batteries," Electrochimica Acta, vol. 317, pp. 583-593, Sept. 2019.
[23] Y. Li, Y. Fu, W. Liu, Y. Song, L. Wang, "Hollow Co-Co3O4@CNTs derived from ZIF-67 for lithium ion batteries," J. Alloys & Compds, vol. 784, pp. 439-446, May 2019.
[24] Q. Tian, Y. Tian, Z. Zhang, L. Yang, S. Hirano, "Fabrication of CNT@void@SnO2@C with tube-in-tube nanostructure as high-performance anode for lithium-ion batteries," J. Power Sources, vol. 291, pp. 173-180, Sept. 2015.
[25] A facile one–pot synthesis of Sn/graphite/graphene nanocomposites as anode materials for lithium–ion batteries, J. Alloys & Compds, vol.809, Article 151870: pp. 1-8, Nov. 2019.
[1] M. Armand and J. M. Tarascon, "Building Better Batteries," Nature, vol. 451, pp. 652-657, Feb. 2008.
[2] K. Nechev, "SAFT's Very High Power Li-Ion Technology," in 3rd Annual International Conference Lithium Mobile Power, San Diego, CA, 2007.
[3] A. Y. Shenouda, "Structure and electrochemical behavior of lithium vanadate materials for lithium batteries," Electrochimica Acta, vol. 51, pp. 5973-5981, May 2006.
[4] A. Y. Shenouda and K.R. Murali, "Electrochemical properties of doped lithium titanate compounds and their performance in lithium rechargeable batteries". J. Power Sources, vol. 176, pp. 332-339, 2008.
[5] A. Y. Shenouda and H. K. Liu, “Electrochemical behaviour of tin borophosphate negative electrodes for energy storage systems,” J. Power Sources, vol. 185, pp. 1386-1391, August 2008.
[6] A. Y. Shenouda, H. K. Liu, "Studies on electrochemical behaviour of zinc-doped LiFePO4 for lithium battery positive electrode," J. Alloys and Compd., vol. 477, pp. 498-503, Dec. 2009.
[7] A. Y. Shenouda, Hua K. Liu, "Preparation, Characterization, and Electrochemical Performance of Li2CuSnO4 and Li2CuSnSiO6 Electrodes for Lithium Batteries," J. Electrochem. Soc., vol. 157, pp. A 1183-A 1187, Nov. 2010.
[8] A.Y. Shenouda E. M. El Sayed and H. K. Liu, "Preparation, Characterization and Electrochemical Performance of LiNixCoyCuzMn2-x-y-zO4 as Positive Electrodes in Lithium Rechargeable Batteries," J. New Materials for Electrochemical Systems", vol. 14, pp. 19-26, Feb. 2011.
[9] S. H. Wu, K.M. Hsiao, W.R. Liu, "The preparation and characterization of olivine LiFePO4 by a solution method," J. Power Sources, vol. 146, pp. 550-554, August 2005.
[10] Q. R. Hu, S. L. Wang, Y. Zhang, W.H. Tang, "Synthesis of cobalt sulfide nanostructures by a facile solvothermal growth process," J. Alloys and Compd., vol. 491, pp. 707–711, Feb. 2010.
[11] S.T. Mane, S. S. Kamble, L.P. Deshmukh, "Cobalt sulphide thin films: Chemical bath deposition, growth and properties," Mater. Letters, vol. 65 pp. 2639–2641, Sept. 2011.
[12] M. Lei, X. L. Fu, Y. B. Zhang, H. J. Yang, Y. T. Huang, L. Zhang, Y. G. Wang, "Synthesis of CoS nanoplates and their ferromagnetic properties," Mater. Letters, vol. 71, pp. 11-14, March 2012.
[13] M. R. Yang, W. H. Ke, S. H. Wu, "Preparation of LiFePO4 powders by co-precipitation," J. Power Sources, vol. 146, pp. 539-543, August 2005.
[14] A. Y. Shenouda and A. A. Momchilov, "A study on graphene/tin oxide performance as negative electrode compound for lithium battery application," J. Materials Science: Materials in Electronics, vol. 30, pp.79–90, Jan. 2019.
[15] J. Feng, S. Xiong, Y. Qian, L. Yin, "Synthesis of nanosized cadmium oxide (CdO) as a novel high capacity anode material for Lithium-ion batteries: influence of carbon nanotubes," Electrochimica Acta, vol. 129, pp. 107–112, Feb. 2014.
[16] F. Zhang, R. Zhang, J. Feng, Y. Qian, CdCO3/Carbon nanotube nanocomposites as anode materials for advanced lithium-ion batteries," Mater. Letters, vol. 114, pp. 115–118, Jan. 2014.
[17] S. Grugeon, S. Laruelle, R. Herrera-Urbina, L. Dupont, P. Poizot, J. M. Tarascon, Particle Size Effects on the Electrochemical Performance of Copper Oxides toward Lithium," J. Electrochem. Soc., vol. 148, pp. A285–A292, April 2001.
[18] P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J. M. Tarascon, "Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries," Nature, vol. 407, pp. 496–499, Sept. 2000.
[19] J. Feng, C. Wang, Y. Qian, "In situ synthesis of cadmium germanates (Cd2Ge2O6)/reduced graphene oxide nanocomposites as novel high capacity anode materials for advanced lithium-ion batteries," Mater. Letters, vol. 122, pp. 327-330, May 2014.
[20] A. L. M. Reddy, M. M. Shaijumon, S.R. Gowda, P.M. Ajayan, "coaxial Mno2/carbon nanotube array electrodes for high-performance lithium batteries," Nano Lett., vol. 9, pp. 1002–1006, March 2009.
[21] Y. Wang, H.C. Zheng, J.Y. Lee, "Highly Reversible Lithium Storage in Porous SnO2 Nanotubes with Coaxially Grown Carbon Nanotube Overlayers," Adv. Mater. vol. 18, pp. 645–649, March 2006.
[22] Q. Wei, G. C. Liu, C. Zhang, X. J. Hong, Y. P. Cai, "Novel honeycomb silicon wrapped in reduced graphene oxide/CNT system as high-stability anodes for lithium-ion batteries," Electrochimica Acta, vol. 317, pp. 583-593, Sept. 2019.
[23] Y. Li, Y. Fu, W. Liu, Y. Song, L. Wang, "Hollow Co-Co3O4@CNTs derived from ZIF-67 for lithium ion batteries," J. Alloys & Compds, vol. 784, pp. 439-446, May 2019.
[24] Q. Tian, Y. Tian, Z. Zhang, L. Yang, S. Hirano, "Fabrication of CNT@void@SnO2@C with tube-in-tube nanostructure as high-performance anode for lithium-ion batteries," J. Power Sources, vol. 291, pp. 173-180, Sept. 2015.
[25] A facile one–pot synthesis of Sn/graphite/graphene nanocomposites as anode materials for lithium–ion batteries, J. Alloys & Compds, vol.809, Article 151870: pp. 1-8, Nov. 2019.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:79798", author = "Atef Y. Shenouda and Anton A. Momchilov", title = "Study on the Electrochemical Performance of Graphene Effect on Cadmium Oxide in Lithium Battery ", abstract = "Graphene and CdO with different stoichiometric ratios of Cd(CH₃COO)₂ and graphene samples were prepared by hydrothermal reaction. The crystalline phases of pure CdO and 3CdO:1graphene were identified by X-ray diffraction (XRD). The particle morphology was studied with SEM. Furthermore, impedance measurements were applied. Galvanostatic measurements for the cells were carried out using potential limits between 0.01 and 3 V vs. Li/Li⁺. The current cycling intensity was 10⁻⁴ A. The specific discharge capacity of 3CdO-1G cell was about 450 Ah.Kg⁻¹ up to more than 100 cycles.", keywords = "CdO, graphene, negative electrode, lithium battery.", volume = "14", number = "8", pages = "196-5", }
