Semi-Transparent Dye-Sensitized Solar Panels for Energy Autonomous Greenhouses
Over 60% highly transparent quasi-solid-state dye-sensitized solar cells (DSSCs) with dimension of 50x50 cm2 were fabricated via inkjet printing process using nanocomposite inks as raw materials and tested under outdoor illumination conditions. The cells were electrically characterized, and their possible application to the shell of greenhouses was also examined. The panel design was in Z-interconnection, where the working electrode was inkjet printed on one conductive glass and the counter electrode on a second glass in a sandwich configuration. Silver current collective fingers were printed on the glasses to make the internal electrical connections. In that case, the adjacent cells were connected in series via silver fingers and finally insulated using a UV curing resin to protect them from the corrosive (I-/I3-) redox couple of the electrolyte.
[1] J. Yan, B.R. Saunders, “Third-generation solar cells: a review and comparison of polymer:fullerene, hybrid polymer and perovskite solar cells”, RSC Advances, vol. 4, pp. 43286-43314, August 2014.
[2] G. Conibeer, “Third generation photovoltaics”, Materials Today, vol. 10, pp. 42-50, November 2007.
[3] S. Khanna, S. Sundaram, K.S. Reddy, T.K. Mallick, “Performance analysis of perovskite and dye-sensitized solar cells under varying operating conditions and comparison with monocrystalline silicon cell” Applied Thermal Engineering, vol. 127, pp. 559-565, December 2017.
[4] A. Hagfeldt, G. Boschloo, L. Sun, L. Kloo, H. Pettersson, “Dye-sensitized solar cells” Chemical reviews, vol. 110, pp. 6595-6663, September 2010.
[5] M. Späth, P.M. Sommeling, J.A.M. van Roosmalen, H.J.P. Smit, N.P.G. van der Burg, D.R. Mahieu, N.J. Bakker, J.M. Kroon, “Reproducible manufacturing of Dye-sensitized solar cells on a semi-automated baseline”, Progress in Photovoltaics: Research and applications, vol. 11, pp. 207-220, February 2003.
[6] F. E. Gálvez, E. Kemppainen, H. Míguez and J. Halme, “Effect of Diffuse Light Scattering Designs on the Efficiency of Dye Solar Cells: An Integral Optical and Electrical Description”, J. Phys. Chem. C, vol. 116, pp. 11426-11433, May 2012.
[7] S. Mathew, A. Yella, P. Gao, R. Humphry-Baker, B. F. E. Curchod, N. Ashari-Astani, I. Tavernelli, U. Rothlisberger, Md. K. Nazeeruddin, M. Grätzel, “Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers”, Nature Chemistry, vol. 6, pp. 242-247, February 2014.
[8] J. Goldstein, I; Yakypov, B. Breen, “Development of large area photovoltaic dye cells at 3GSolar”, Solar Energy Materials and Solar cells, vol. 94, pp. 638-641, April 2010.
[9] G. R. A. Kumara, S. Kawasaki, P. V. V. Jayaweera, E. V. A. Premalal, S. Kaneko, “Large area dye-sensitized solar cells with titanium based counter electrode”, Thin Solid Films, vol. 520, pp. 4119-4121, April 2011.
[10] D. Sygkridou, A. Rapsomanikis, E. Stathatos, “Functional transparent quasi-solid state dye-sensitized solar cells made with different oligomer organic/inorganic hybrid electrolytes”, Solar Energy Materials & Solar Cells vol. 159 pp. 600–607, January 2017.
[11] E. Stathatos, “Organic-inorganic nanocomposite materials prepared by the sol-gel route as new ionic conductors in quasi solid state electrolytes”, Ionics, vol. 11, pp. 140–145, November 2004.
[12] E. Stathatos, P. Lianos, U. L. Stangar, B. Orel, and P. Judeinstein, “Structural study of hybrid organic/inorganic polymer gels using time-resolved fluorescence probing”, Langmuir, vol. 16, pp. 8672–8676, June 2000.
[1] J. Yan, B.R. Saunders, “Third-generation solar cells: a review and comparison of polymer:fullerene, hybrid polymer and perovskite solar cells”, RSC Advances, vol. 4, pp. 43286-43314, August 2014.
[2] G. Conibeer, “Third generation photovoltaics”, Materials Today, vol. 10, pp. 42-50, November 2007.
[3] S. Khanna, S. Sundaram, K.S. Reddy, T.K. Mallick, “Performance analysis of perovskite and dye-sensitized solar cells under varying operating conditions and comparison with monocrystalline silicon cell” Applied Thermal Engineering, vol. 127, pp. 559-565, December 2017.
[4] A. Hagfeldt, G. Boschloo, L. Sun, L. Kloo, H. Pettersson, “Dye-sensitized solar cells” Chemical reviews, vol. 110, pp. 6595-6663, September 2010.
[5] M. Späth, P.M. Sommeling, J.A.M. van Roosmalen, H.J.P. Smit, N.P.G. van der Burg, D.R. Mahieu, N.J. Bakker, J.M. Kroon, “Reproducible manufacturing of Dye-sensitized solar cells on a semi-automated baseline”, Progress in Photovoltaics: Research and applications, vol. 11, pp. 207-220, February 2003.
[6] F. E. Gálvez, E. Kemppainen, H. Míguez and J. Halme, “Effect of Diffuse Light Scattering Designs on the Efficiency of Dye Solar Cells: An Integral Optical and Electrical Description”, J. Phys. Chem. C, vol. 116, pp. 11426-11433, May 2012.
[7] S. Mathew, A. Yella, P. Gao, R. Humphry-Baker, B. F. E. Curchod, N. Ashari-Astani, I. Tavernelli, U. Rothlisberger, Md. K. Nazeeruddin, M. Grätzel, “Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers”, Nature Chemistry, vol. 6, pp. 242-247, February 2014.
[8] J. Goldstein, I; Yakypov, B. Breen, “Development of large area photovoltaic dye cells at 3GSolar”, Solar Energy Materials and Solar cells, vol. 94, pp. 638-641, April 2010.
[9] G. R. A. Kumara, S. Kawasaki, P. V. V. Jayaweera, E. V. A. Premalal, S. Kaneko, “Large area dye-sensitized solar cells with titanium based counter electrode”, Thin Solid Films, vol. 520, pp. 4119-4121, April 2011.
[10] D. Sygkridou, A. Rapsomanikis, E. Stathatos, “Functional transparent quasi-solid state dye-sensitized solar cells made with different oligomer organic/inorganic hybrid electrolytes”, Solar Energy Materials & Solar Cells vol. 159 pp. 600–607, January 2017.
[11] E. Stathatos, “Organic-inorganic nanocomposite materials prepared by the sol-gel route as new ionic conductors in quasi solid state electrolytes”, Ionics, vol. 11, pp. 140–145, November 2004.
[12] E. Stathatos, P. Lianos, U. L. Stangar, B. Orel, and P. Judeinstein, “Structural study of hybrid organic/inorganic polymer gels using time-resolved fluorescence probing”, Langmuir, vol. 16, pp. 8672–8676, June 2000.
@article{"International Journal of Architectural, Civil and Construction Sciences:79502", author = "A. Mourtzikou and D. Sygkridou and T. Georgakopoulos and G. Katsagounos and E. Stathatos", title = "Semi-Transparent Dye-Sensitized Solar Panels for Energy Autonomous Greenhouses", abstract = "Over 60% highly transparent quasi-solid-state dye-sensitized solar cells (DSSCs) with dimension of 50x50 cm2 were fabricated via inkjet printing process using nanocomposite inks as raw materials and tested under outdoor illumination conditions. The cells were electrically characterized, and their possible application to the shell of greenhouses was also examined. The panel design was in Z-interconnection, where the working electrode was inkjet printed on one conductive glass and the counter electrode on a second glass in a sandwich configuration. Silver current collective fingers were printed on the glasses to make the internal electrical connections. In that case, the adjacent cells were connected in series via silver fingers and finally insulated using a UV curing resin to protect them from the corrosive (I-/I3-) redox couple of the electrolyte.
", keywords = "Dye-sensitized solar panels, inkjet printing, quasi-solid-state electrolyte, semi-transparency, scale up.", volume = "14", number = "3", pages = "90-6", }
